investigations of cracks propagating at up to 2.5 km s along an (001) plane of a silicon single crystal are reported, using X-ray diffraction megahertz imaging with intense and time-structured synchrotron radiation. The studied system is based on the Smart Cut process, where a buried layer in a material (typically Si) is weakened by microcracks and then used to drive a macroscopic crack (10 m) in a plane parallel to the surface with minimal deviation (10 m). A direct confirmation that the shape of the crack front is not affected by the distribution of the microcracks is provided. Instantaneous crack velocities over the centimetre-wide field of view were measured and showed an effect of local heating by the X-ray beam. The post-crack movements of the separated wafer parts could also be observed and explained using pneumatics and elasticity. A comprehensive view of controlled fracture propagation in a crystalline material is provided, paving the way for the measurement of ultra-fast strain field propagation.
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http://dx.doi.org/10.1107/S1600576722006537 | DOI Listing |
Sci Rep
January 2025
Depto de Química, Universidade Federal de Minas Gerais, Belo Horizonte, MG, CEP 31.270-901, Brazil.
Magnetoliposomes containing magnetite, soy lecithin, stigmasterol, and beta-sitosterol of the mean size minor than 160 nm were obtained by a scalable and green process using autoclave and sonication without organic solvents. The formation, size of the liposome, linkage, and encapsulation of the magnetite were evaluated by Cryo-TEM. The stability of magnetoliposomes after storage for 6 months at 4 °C was improved by liposome size, the ability of soy lecithin to preserve the magnetite phase against oxidation, pH, polydispersity index, and zeta potential.
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January 2025
NMR-based Structural Biology, Max Planck Institute for Multidisciplinary Sciences, Göttingen, Germany.
Membrane bound histidine kinases (HKs) are ubiquitous sensors of extracellular stimuli in bacteria. However, a uniform structural model is still missing for their transmembrane signaling mechanism. Here, we used solid-state NMR in conjunction with crystallography, solution NMR and distance measurements to investigate the transmembrane signaling mechanism of a paradigmatic citrate sensing membrane embedded HK, CitA.
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January 2025
College of Mechanical and Transportation Engineering, Southwest Forestry University, Kunming, 650224, China.
The current piston material, Al-12Si, lacks sufficient passivation in the acidic lubrication system of biodiesel engines, making it prone to corrosion in the presence of Cl. Fe amorphous particles exhibit good compatibility with Al-12Si, possessing strong corrosion resistance, excellent passivation ability, and good high-temperature stability. They are a potential reinforcement for enhancing the Al-12Si piston material.
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January 2025
Cold Spring Harbor Laboratory, One Bungtown Road, Cold Spring Harbor, New York, 11724, USA.
Glycation, a non-enzymatic post-translational modification occurring on proteins, can be actively reversed via site-specific phosphorylation of the fructose-lysine moiety by FN3K kinase, to impact the cellular function of the target protein. A regulatory axis between FN3K and glycated protein targets has been associated with conditions like diabetes and cancer. However, the molecular basis of this relationship has not been explored so far.
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January 2025
Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, University of Science and Technology, 16846-13114, Tehran, Iran.
In this research, graphene oxide-polyaniline (GO-PANI) nanocomposite was successfully synthesized and its catalytic performance was evaluated for the synthesis of N-aryl-1,4-dihydropyridine (1,4-DHP) and hydroquinoline derivatives. The GO nanosheets were prepared using the Hummers' method, and in-situ polymerization of aniline was conducted with ammonium persulfate (APS) serving as the polymerization initiator. The synthesized nanocomposite demonstrated notable efficiency, achieving yields of 80-94% for 1,4-DHP derivatives and 84-96% for hydroquinoline derivatives.
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