Electronic structure modulation of multi-walled carbon nanotubes using azo dye for inducing non-radical reaction: Effect of graphitic nitrogen and structural defect.

Multiwalled carbon nanotube (MWCNT) have a great potential for advanced oxidation process as a metal free catalyst. However, there catalytic activity is very low and needs to be appropriately tuned. Herein, we demonstrate a novel synthesis method for tuning the defect and surface functionality of MWCNT using azo dyes and the catalytic performance was tested for the degradation of different organic contaminates using PMS as an oxidant. The content, type of heteroatom functional groups, and the defect parameters were optimized by varying the pH and concentration of the organic dye. The quenching effect showed that singlet oxygen (O) is the primary reactive species generated by graphitic nitrogen, which can be boosted by the degree of graphitic structure disruption in MWCNT. The Linear sweep voltammetry (LSV) also confirmed that extrinsic doping enhanced the non-radical degradation by increasing the direct charge transfer rate from MB to PMS. Moreover, the designed catalyst showed a fast degradation performance with 35.1 kJ/mol activation energy and achieved the highest dye degradation rate and even surpassed some state-of-the-art metal-based and metal-free catalysts. The effect of inorganic anions study has also confirmed its industrial applicability.