Formic acid (FA), as a safe and renewable liquid hydrogen storage material, has attracted extensive attention. In this paper, a series of Mo-modified pseudoboehmite supported Ni catalysts were developed and evaluated for efficient hydrogen production from formic acid. Pseudoboehmite (PB) as a catalyst carrier was used for the first time. Ni/PB and NiMo/PB possessed a mesostructure, and the pore size distribution was mainly concentrated between 2 and 20 nm. The oxygen vacancies caused by Mo enhanced Ni anchoring, thus inhibiting Ni sintering. Compared with Ni10/PB (7.62 nm), Ni10Mo1/PB had smaller Ni particles (5.08 nm). The Ni-O-Al solid solutions formed through the interaction of Ni with the PB improved the catalytic performance. Ni10Mo1/PB gave the highest conversion of 92.8% with a H selectivity of 98% at 300 °C, and the catalyst activity hardly decreased during the 50 h stability test. In short, Ni10Mo1/PB was a promising catalyst for hydrogen production from formic acid because of the oxygen vacancy anchoring effect as well as the formation of Ni-O-Al solid solutions which could effectively suppress the Ni sintering.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9366974PMC
http://dx.doi.org/10.1021/acsomega.2c01742DOI Listing

Publication Analysis

Top Keywords

formic acid
16
hydrogen production
12
production formic
12
mo-modified pseudoboehmite
8
pseudoboehmite supported
8
supported catalysts
8
efficient hydrogen
8
ni-o-al solid
8
solid solutions
8
development mo-modified
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!