Air packaging is obviously beneficial to the heterogeneous hygrothermal degradation of konjac glucomannan.

Heterogeneous hygrothermal degradation (HHTD) is a cost-effective and environmentally friendly method for the successful preparation of partially depolymerized konjac glucomannan (DKGM). This study investigated the degradation of konjac glucomannan (KGM) in two packaging methods and detected that compared with natural KGM, the M of vacuum-packaged DKGM with 20 % moisture content treated at 130 °C for 40 min was reduced by 23.34 %, while that of air-packaged DKGM was decreased by 63.14 %, the vacuum-packaged DKGM with only 0.5 % HO added was dropped by 69.36 %. It was verified that oxygen in air-packaging plays a crucial role in HHTD. Furthermore, the effects of moisture content, treatment temperature and time on the M and apparent viscosity of air-packaged DKGM were explored. The properties and structure of DKGM were characterized by rheometer, TGA, XRD, FT-IR and SEM. Results established that treatment temperature had a stronger promoting effect on HHTD. The rheological properties of DKGM samples changed markedly, and the thermal decomposition temperature and crystallinity were increased, with its infrared absorption peaks very close. This research is expected to provide theoretical bases and reference ideas for efficient HHTD method of KGM in actual production.