Mechanisms of Ni removal from contaminated groundwater by calcite using X-ray absorption spectroscopy and Ni isotope measurements.

A flow-through cell (FTC) experiment was conducted to identify mechanisms of Ni removal by calcite through study of changes in Ni speciation and Ni isotope signature during the treatment of simulated Ni-contaminated groundwater. Synthetic Ni-contaminated groundwater was pumped through a FTC packed with crushed natural calcite. Effluent samples were collected to determine concentrations of anions, cations, and for Ni isotope-ratio measurement. X-ray absorption spectroscopy (XAS) was performed on chosen spots of the solid phase along the FTC length. Isotope data indicated multiple mechanisms affected Ni removal in the FTC system. Ni adsorption to and coprecipitation with calcite dominated the early part of the experiment yielding a fractionation factor of ε = -0.5 ‰. Subsequently, Ni precipitation as a Ni-hydroxide phase became the major process controlling Ni removal, resulting in a fractionation factor ε = -0.4 ‰. XAS analysis confirmed the presence of both Ni(OH) and (Ni, Ca)CO types of Ni local structural environments. Results from this study highlight the potential of Ni isotopes as auxiliary tools to determine the processes involved in Ni attenuation from the environment. The characterization of mechanisms involved in Ni removal from solution is necessary to evaluate potential impacts to the environment and to develop effective remediation strategies.