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A Tail Does Not Always Make a Difference: Assembly of Nets from Co(NCS) and 1,4-bis(-Alkyloxy)-2,5-bis(3,2':6',3″-terpyridin-4'-yl)benzene Ligands. | LitMetric
The consistent assembly of a (6.8) net is observed in reactions of cobalt(II) thiocyanate with 1,4-bis(-alkyloxy)-2,5-bis(3,2':6',3″-terpyridin-4'-yl)benzene ligands in which the alkyloxy substituents are -propyl (ligand ), -butyl (), -pentyl (), -hexyl (), -heptyl (), and -octyl (). Crystals were grown by layering a methanol solution of Co(NCS) over a 1,2-dichlorobenzene solution of each ligand. The choice of crystallization solvents is critical in directing the assembly of the net. Single-crystal structures of [Co(NCS)()]3.5CHCl, [Co(NCS)()]5.5CHCl, [Co(NCS)()]4CHCl, [Co(NCS)()]3.8CHCl, [Co(NCS)()]3.1CHCl, and [Co(NCS)()]1.6CHCl2MeOH (CHCl = 1,2-dichlorobenzene) are presented and compared. The alkyloxy chains exhibit close to extended conformations and are accommodated in cavities in the lattice without perturbation of the coordination framework.
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