This paper reviews the state-of-the-art technologies, characterizations, materials (precursors and encapsulants), and challenges concerning multicolor and white light-emitting diodes (LEDs) based on carbon dots (CDs) as color converters. Herein, CDs are exploited to achieve emission in LEDs at wavelengths longer than the pump wavelength. White LEDs are typically obtained by pumping broad band visible-emitting CDs by an UV LED, or yellow-green-emitting CDs by a blue LED. The most important methods used to produce CDs, top-down and bottom-up, are described in detail, together with the process that allows one to embed the synthetized CDs on the surface of the pumping LEDs. Experimental results show that CDs are very promising ecofriendly candidates with the potential to replace phosphors in traditional color conversion LEDs. The future for these devices is bright, but several goals must still be achieved to reach full maturity.
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http://dx.doi.org/10.3390/ma15155450 | DOI Listing |
Inorg Chem
January 2025
College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, P.R. China.
Phosphors with broadband green emission are highly desirable for the construction of high-color-rendering warm-white light-emitting diode (LED) devices toward healthy solid-state lighting applications. However, most of the reported green phosphors are subject to an undesirable emission bandwidth and low quantum efficiency. Here, a highly efficient broadband green-emitting garnet phosphor, CaLuScAlSiO:Ce (CLSASO:Ce), is successfully synthesized and investigated in detail.
View Article and Find Full Text PDFOrg Lett
January 2025
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
Hindered tetraphenylethylene (hTPE) helicates are resolved into two left-handed (M) and right-handed (P) isomers by linkage and removal of chiral auxiliary (1,2,5)-menthol, furnishing gram-scale hTPE enantiomers via flash silica column chromatography. hTPE helicate enantiomers bearing electron-accepting cyano and electron-donating triphenylamine groups can emit deep-blue CPL signals with a fluorescence quantum yield surpassing 50%. Full-color and white-light emission were achieved by blending them with dyes in a poly(methyl methacrylate) (PMMA) film.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Colour Science and Textile Chemistry Research Center, College of Textiles and Clothing, Qingdao University, Qingdao, Shandong 266071, China.
Superhydrophobic fabrics suffer from being commonly penetrated by moisture after laundering, seriously deteriorating their water repellency after air drying. Numerous researchers have successfully recovered superhydrophobicity by drying in fluid ovens; however, high energy consumption and equipment dependence limit practical applications. Herein, the superhydrophobic photothermal self-healing cotton fabric (SPS cotton fabric) was fabricated by depositing a composite layer of cellulose nanocrystal-MXene (C-MXene) and polyacrylate (PA) coatings on the cotton cloth.
View Article and Find Full Text PDFJ Opt Soc Am A Opt Image Sci Vis
August 2024
In order to improve the accuracy of camera colorimetric characterization, a multi-input parameter optimization method was proposed in this paper. The input parameters of the traditional camera characterization method were generally RGB values; in the proposed method, the luminance parameter L was introduced in addition to RGB values, and the four-input parameters of RGBL were used as input parameters for the conversion model. In the experiment, 549 colors were uniformly selected from the Munsell Book of Color (Matte Edition), and the RGBL values and corresponding CIEXYZ values of the selected colors were measured by a spectroradiometer and three cameras, including an imaging luminance meter, respectively.
View Article and Find Full Text PDFDalton Trans
January 2025
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China.
Nowadays, benzimidazole and its derivatives are widely assembled into multifunctional materials with various properties such as mechanochromism, photochromism, thermochromism and electrochromism. Herein, two novel zinc(II) coordination compounds, [Zn(L)Br]·2HO (1) and [Zn(L)Cl]·2HO (2) (L = tetra(1-benzo[]imidazol-2-yl)ethene), have been constructed one-pot facile synthesis from bis(1-benzo[]imidazol-2-yl)methane (L) and zinc(II) salts. The ligand L with a CC double bond was formed by C-C coupling of two sp-C atoms of L in solvothermal synthesis, which provides a new strategy to generate the conjugation system conveniently.
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