Pentavalent complex of 99Mo with ascorbic acid binds in vitro to the plasma membranes of human, rabbit, rat and mouse red cell membranes and to bovine synaptic and rat intestinal brush border membranes. Red cell spectrins and spectrin-like proteins from non-erythroid cells were determined as the molybdenum-binding proteins in the membranes. Specificity of this binding among all membrane proteins suggests structural analogy in this group of proteins.
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http://dx.doi.org/10.1016/0305-0491(87)90443-3 | DOI Listing |
Soft Robot
December 2024
Department of Surgical & Interventional Engineering, School of Biomedical Engineering & Imaging Sciences, King's College London (KCL), London, UK.
Modern industrial and medical applications require soft actuators with practical actuation methods, capable of precision control and high-speed performance. Within the realm of medical robotics, precision and speed imply less complications and reduced operational times. Soft fluidic actuators (SFAs) are promising candidates to replace the current rigid endoscopes due to their mechanical compliance, which offers safer human-robot interaction.
View Article and Find Full Text PDFNew Phytol
December 2024
PFR, Chemistry Department, University of Otago, Dunedin, 9016, New Zealand.
The potential of cannabinoids to address public health challenges has stimulated exploration into alternative sources and production technologies. Radula marginata, an endemic Aotearoa/New Zealand liverwort, produces the bibenzyl cannabinoid perrottetinene (PET), analogous to Cannabis psychoactive tetrahydrocannabinol (THC). Structural differences between PET and THC could alter therapeutic interactions and mitigate adverse side effects.
View Article and Find Full Text PDFNature
December 2024
Department of Chemistry, Scripps Research, La Jolla, California, USA.
The synthesis of a complex molecule begins from an initial design stage in which possible routes are triaged by strategy and feasibility, based on analogy to similar reactions. However, as molecular complexity increases, predictability decreases; inevitably, even experienced chemists resort to trial-and-error to identify viable intermediates en route to the target molecule. We encountered such a problem in the synthesis of picrotoxane sesquiterpenes in which pattern recognition methods anticipated success, but small variations in structure led to failure.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
School of Physics, Peking University, Beijing 100871, China.
In recent years, energy correlators have emerged as a powerful tool to explore the field theoretic structure of strong interactions at particle colliders. In this Letter we initiate a novel study of the nonperturbative power corrections to the projected N-point energy correlators in the limit where the angle between the detectors is small. Using the light-ray operator product expansion as a guiding principle, we derive the power corrections in terms of two nonperturbative quantities describing the fragmentation of quarks and gluons.
View Article and Find Full Text PDFACS Nanosci Au
December 2024
Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.
Colloidal nanoparticle assembly methods can produce intricate superlattice structures and often use knowledge of atomic crystallization behaviors to guide their design. While this analogy has enabled multiple routes to programming colloidal crystallization thermodynamics, fewer tools or strategies exist to manipulate nanoparticle superlattice growth kinetics in a controlled manner. Here we investigate how small-molecule additives can be used to modulate the thermodynamics and kinetics of supramolecular-chemistry-driven nanoparticle assembly.
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