Low-valent uranium(III) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy (H, B, P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.
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| http://dx.doi.org/10.1039/d2cc02207a | DOI Listing |
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