Invited for the cover of this issue is the group of Ewa Pacholska-Dudziak at the University of Wroclaw. The image depicts two rhodium atoms being fixed into the skeleton of 21,23-dirhodaporphyrin in place of two core nitrogen donors. Read the full text of the article at 10.1002/chem.202201513.
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Anticancer Study on Ir and Rh Half-Sandwich Complexes with the Bipyridylsulfonamide Ligand.
Inorg Chem
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Faculty of Chemistry, University of Gdańsk, Wita Stwosza 63, 80-308 Gdańsk, Poland.
Organometallic half-sandwich complexes [(η-Cp)IrCl(L)]PF () and [(η-Cp)RhCl(L)]PF () were prepared using pentamethylcyclopentadienyl chloride dimers of iridium(III) or rhodium(III) with the 4-amino--(2,2'-bipyridin-5-yl)benzenesulfonamide ligand () and ammonium hexafluorophosphate. The crystal structures of , , and were analyzed in detail. The coordination reactions of the ligand with the central ions were confirmed using various spectroscopic techniques.
View Article and Find Full Text PDFSynthesis and photothermal conversion properties of sandwich N-fused porphyrin rhodium-μ-dichloride dimer complexes: π-extended analog of pentamethylcyclopentadienyl dirhodium(III)-μ-dichloride dimer.
J Inorg Biochem
February 2024
Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan. Electronic address:
Article Synopsis
- - The study focuses on anionic cyclopentadienyl (Cp) and its modified version (Cp*) as important ligands for creating stable materials, including catalysts, and explores their structural counterpart, N-fused porphyrin (NFP), which has useful near-infrared (NIR) optical properties.
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Department of Inorganic Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University, Maria Curie-Skłodowska Sq. 2, 20-031 Lublin, Poland.
Noble metals (NM) such as gold, platinum, palladium, and rhodium are widely applied in the electronics and automotive industries. Thus, the search for cheap and selective sorbents for noble metals is economically justified. Nitrolite does not sorb noble metal ions.
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Anal Chim Acta
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Key Laboratory of Luminescence Analysis and Molecular Sensing, Ministry of Education, School of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400715, PR China. Electronic address:
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View Article and Find Full Text PDFTwo Rhodium(III) Ions Confined in a [18]Porphyrin Frame: 5,10,15,20-Tetraaryl-21,23-dirhodaporphyrin.
Chemistry
August 2022
Faculty of Chemistry, University of Wroclaw, ul. Joliot-Curie 14, 50-383, Wroclaw, Poland.
Invited for the cover of this issue is the group of Ewa Pacholska-Dudziak at the University of Wroclaw. The image depicts two rhodium atoms being fixed into the skeleton of 21,23-dirhodaporphyrin in place of two core nitrogen donors. Read the full text of the article at 10.
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