Herein, we report the B(C F ) -catalyzed E-selective isomerization of alkenes. The transition-metal-free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804281 | PMC |
| http://dx.doi.org/10.1002/chem.202202454 | DOI Listing |
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