Grasslands store approximately one third of the global terrestrial carbon stocks and can act as an important soil carbon sink. Recent studies show that plant diversity increases soil organic carbon (SOC) storage by elevating carbon inputs to belowground biomass and promoting microbial necromass contribution to SOC storage. Climate change affects grassland SOC storage by modifying the processes of plant carbon inputs and microbial catabolism and anabolism. Improved grazing management and biodiversity restoration can provide low-cost and/or high-carbon-gain options for natural climate solutions in global grasslands. The achievable SOC sequestration potential in global grasslands is 2.3 to 7.3 billion tons of carbon dioxide equivalents per year (COe year) for biodiversity restoration, 148 to 699 megatons of COe year for improved grazing management, and 147 megatons of COe year for sown legumes in pasturelands.
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http://dx.doi.org/10.1126/science.abo2380 | DOI Listing |
J Am Chem Soc
January 2025
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan.
High-performance and cost-effective hole-collecting materials (HCMs) are indispensable for commercially viable perovskite solar cells (PSCs). Here, we report an anchorable HCM composed of a triazatruxene core connected with three alkyl carboxylic acid groups (). In contrast to the phosphonic acid-containing tripodal analog (), molecules can form a hydrophilic monolayer on a transparent conducting oxide surface, which is beneficial for subsequent perovskite film deposition in the traditional layer-by-layer fabrication process.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Materials Science, Fudan University, Shanghai 200433, China.
Borohydrides, known for ultrahigh hydrogen density, are promising hydrogen storage materials but typically require high operating temperatures due to their strong thermodynamic stability. Here we introduce a novel light-induced destabilization mechanism for hydrogen storage reaction of borohydrides under ambient conditions photogenerated vacancies in LiH. These vacancies thermodynamically destabilize B-H bonds through the spontaneous "strong adsorption" of BH groups, which trigger an asymmetric redistribution of electrons, enabling hydrogen release at near room temperature, approximately 300 °C lower than the corresponding thermal process.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Northwestern University, Technological Institute, Evanston, Illinois 60208, United States.
Recent advances in redox flow batteries have made them a viable option for grid-scale energy storage, however they exhibit low energy density. One way to boost energy density is by increasing the cell potential using a nonaqueous system. Molecular engineering has proven to be an effective strategy to develop redox-active compounds with extreme potentials but these are usually challenged by resource sustainability of the newly developed redox materials.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
School of Materials Science and Engineering, Tianjin Key Laboratory of Metal and Molecular Materials Chemistry, Frontiers Science Center for New Organic Matter, Nankai University, Tongyan Road 38, Tianjin 300350, P. R. China.
Flexible molecular crystals are essential for advancing smart materials, providing unique functionality and adaptability for applications in next-generation electronics, pharmaceuticals, and energy storage. However, the optical applications of flexible molecular crystals have been largely restricted to linear optics, with nonlinear optical (NLO) properties rarely explored. Herein, we report on the application of mechanical twisting of flexible molecular crystals for second-order nonlinear optics.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Dankook University, 119, Dandae-ro, Chungnam 448-701, Korea.
This paper presents the reversible transformation between two polymorphs of a hexacatenar liquid crystal () with distinct fluorescence colors at room temperature (RT). This method utilizes mechanical pressure (mechanochromism) and an electric field (E-field-chromism). The molecule (), designed with a pyrene core and 1,2,3-triazole linkers, exhibits a blue-emissive crystalline (CRY) polymorph () and a green-emissive liquid crystalline (LC) polymorph () at RT, depending on the cooling rate from the liquid phase.
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