By using glycidol as a catalyst, high porosity, low-density resorcinol (R) and formaldehyde (F) aerogels and carbon aerogels (CAs) were synthesized a sol-gel method. The effect of glycidol and water on the color, density, morphology, textual characteristics and adsorption properties of the resultant RF aerogels and CAs were investigated in detail. The results revealed that the properties of RF aerogels and CAs can be controlled by adjusting the amount of glycidol and water. The resultant RF aerogels and CAs were porous materials, the minimum densities of RF aerogels and CAs were 96 and 110 mg cm respectively while the maximum specific surface areas of RF aerogels and CAs were 290 and 597 m g. The maximum adsorption capacity of CAs was about 125 mg g on Rhodamine B, which was higher than that of some reported CAs catalyzed by base and acid catalysts. The sol-gel mechanisms of RF aerogels and CAs can be attributed to the opening of the epoxy group of glycidol in the mixture of R and F.
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http://dx.doi.org/10.1039/d2ra03270h | DOI Listing |
Int J Biol Macromol
January 2025
School of Light Industry & Chemical Engineering, Dalian Polytechnic University, Dalian 116034, PR China. Electronic address:
In this work, a new biomass boron adsorbent of N-methyl-D-glucosamine embedded sodium alginate/polyethyleneimine/polysiloxane composite aerogel (SKPN) was reported. Relevant characterization proved that the aerogel exhibited 3D porous structure with plenty of hydroxyl and amino functional groups, which was beneficial to the diffusion of boron and the chelation between boron and SKPN. Various parameters affecting the adsorption performance including pH value, contact time initial concentration, temperature and reusability were investigated.
View Article and Find Full Text PDFACS Nano
January 2025
CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, University of Science and Technology of China, Hefei, Anhui 230027, PR China.
Flexible on-skin electronics present tremendous popularity in intelligent electronic skins (e-skins), healthcare monitoring, and human-machine interfaces. However, the reported e-skins can hardly provide high permeability, good stretchability, and large sensitivity and are limited in long-term stability and efficient recyclability when worn on the human body. Herein, inspired from the human skin, a permeable, stretchable, and recyclable cellulose aerogel-based electronic system is developed by sandwiching a screen-printed silver sensing layer between a biocompatible CNF/HPC/PVA (cellulose nanofiber/hydroxypropyl cellulose/poly(vinyl alcohol)) aerogel hypodermis layer and a permeable polyurethane layer as the epidermis layer.
View Article and Find Full Text PDFMolecules
November 2024
Department of Basic and Applied Sciences for Engineering (SBAI), Sapienza University of Rome, Via A. Scarpa 14, 00161 Rome, Italy.
ACS Appl Mater Interfaces
December 2024
School of Nano-Tech and Nano-Bionics, University of Science and Technology of China (USTC), Hefei 230026, China.
Humans possess the remarkable ability to perceive the intricate world by integrating multiple senses. However, the challenge of enabling humanoid robots to achieve multimodal sensing and fine recognition of metallic materials persists. In this study, we propose a flexible tactile sensor that mimics the sensory patterns of human skin, which is assembled by a flexible electromagnetic coil that is engraved on the surface of a polyimide substrate and porous MXene/CNT aerogel.
View Article and Find Full Text PDFGels
November 2024
Instituto Politécnico Nacional CICATA, Legaria, Mexico City 11500, Mexico.
This study compared the chemical, structural, and luminescent properties of xerogel-based ceramic powders (CPs) with those of a new series of crystallized aerogels (CAs) synthesized by the epoxy-assisted sol-gel process. Materials with different proportions of Eu (2, 5, 8, and 10 mol%) were synthesized in LuO host matrices, as well as a EuO matrix for comparative purposes. The products were analyzed by infrared spectroscopy (IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), transmission electron microscopy (TEM), photoluminescence analysis, and by the Brunauer-Emmett-Teller (BET) technique.
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