Compacted clay barriers have been used to retard leakage of contaminated fluids from landfillsites. These liners may shrink, crack, desiccate and lose their integrity if the liner material doesn't have permeability (10 m/s), unconfined compressive strength (UCS = 200 kPa) and no desiccation cracks at all as per the CPCB-2001 and USEPA 1989 guidelines. These three parameters form the basis of utilizing any material as a liner material however bentonite clay (BC) due to excessive desiccation cracks upon drying and wetting events can't be used individually. The usual practice to overcome failure, of barrier material the usual practice is to amend BC with sand though being costly and unsustainable. Recently, Fly ash (FA) and Coal ash (CA) byproducts from thermal power plant, have been explored as a substitute of sand in landfill liner material for sustainable practices. The purpose of this study is to investigate and and compare the various composition of B-FA and B-CA in terms of adequate strength, permeability, and shrinkage/desiccation in such a way to meet the CPCB-2001 and USEPA 1989 guidelines. The variation of specific gravity, liquid limit, plastic limit, and DFSI with varying compositions of bentonite was also studied. The present study demonstrates that with the increment of BC permeability was found to decrease and 80CA20B, 80FA20B, 80FA15B5CA combinations were meeting CPCB-2001 permeability criterion. To replicate the field condition the overburdening pressure was varied from 100 to 800 kPa and the permeability was found to be within the prescribed range for the three compositions. In total, 72 UCS, including triplicates for 7, 14 and 28 days, were conducted to see if any pozzolanic reaction was ensuingand its effect on the strength. The maximum UCS was found to be 302 kPa for 80CA20B composition while 277 kPa for 80FA20B. Strength Improvement Factor (SIF) and Mobilized peak strain factor (MPSF) were found to be maximum for the 80CA20B composition for 28 days as 1.54 and 0.44 respectively. The composition 80CA20B demonstrated better desiccation crack resistance behaviour than 80FA20B and 80FA15B5CA. The volumetric shrinkage for 80CA20B, 80FA20B and 80FA15B5CA were 4.6, 10.49 and 4.2%. Further, there were no desiccation cracks observed if the volumetric shrinkage is around 4%. The water retention behavior of all the three compositions was almost same. The microstructure analysis for morphology, compositional characterization, and thermal analysis of the various constituents was also carried out.
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http://dx.doi.org/10.1016/j.envres.2022.113853 | DOI Listing |
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