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Solvent Gaming Chemistry to Control the Quality of Halide Perovskite Thin Films for Photovoltaics. | LitMetric

Solvent Gaming Chemistry to Control the Quality of Halide Perovskite Thin Films for Photovoltaics.

ACS Cent Sci

State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, China.

Published: July 2022

AI Article Synopsis

  • Research on solvent chemistry for halide perovskite intermediates is crucial for advancing perovskite solar cells (PSCs) for commercial use.
  • The study reveals how solvent basicity influences bonding with FA or Pb cations, creating two distinct intermediate structures.
  • The findings suggest that choosing solvents based on their basicity can lead to defect-free perovskite films, improving the performance of PSCs.

Article Abstract

Research on solvent chemistry, particularly for halide perovskite intermediates, has been advancing the development of perovskite solar cells (PSCs) toward commercial applications. A predictive understanding of solvent effects on the perovskite formation is thus essential. This work systematically discloses the relationship among the basicity of solvents, solvent-contained intermediate structures, and intermediate-to-perovskite α-FAPbI evolutions. Depending on their basicity, solvents exhibit their own favorite bonding selection with FA or Pb cations by forming either hydrogen bonds or coordination bonds, resulting in two different kinds of intermediate structures. While both intermediates can be evolved into α-FAPbI below the δ-to-α thermodynamic temperature, the hydrogen-bond-favorable kind could form defect-less α-FAPbI via sidestepping the break of strong coordination bonds. The disclosed solvent gaming mechanism guides the solvent selection for fabricating high-quality perovskite films and thus high-performance PSCs and modules.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9336153PMC
http://dx.doi.org/10.1021/acscentsci.2c00385DOI Listing

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