Low-cost and low-input water treatment systems are important for industrial stormwater remediation. Here we examine a flow-through reactor treatment installation where water exceeds the allowable maximum concentration for drinking water in multiple metals (e.g., chromium [Cr], cadmium [Cd], zinc [Zn]) prior to treatment. Specifically, we seek to understand why Cr attenuated in the reactors is not leachable by identifying the specific chemical form of Cr and dominant mechanisms promoting sequestration in the reactors. Total solid-phase Cr concentration in the peat media ranged from 50 to 150 mg/kg after 1 yr of exposure to stormwater to 300 to 900 mg/kg after 3.5 yr. X-ray fluorescence mapping images show Cr, iron (Fe), and Zn spatially correlated over a scale of 10 μm to 5 mm. Chromium rinds form on the edges of peat particles as Cr accumulates. Chromium and Fe K-edge X-ray absorption near edge structure spectroscopy reveal chromium predominately in the 3+ oxidation state with lesser amounts of elemental Cr. We propose the primary means of chromium attenuation in the reactors is precipitation as Cr-Fe hydroxides combined with trivalent Cr adsorption onto peat surfaces.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/jeq2.20397 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
From Anatase TiO Nano-Cuboids to Nano-Bipyramids: Influence of Particle Shape on the TiO Photocatalytic Degradation of Emerging Contaminants in Contrasted Water Matrices.
Molecules
January 2025
Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain.
Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices.
View Article and Find Full Text PDFSurveillance and environmental risk of very mobile pollutants in urban stormwater and rainwater in a water-stressed city.
J Hazard Mater
December 2024
ONHEALTH, IDAEA-CSIC, Jordi Girona 18-26, Barcelona 08034, Spain. Electronic address:
Urban stormwater and rainwater in water-stressed cities serve as critical vectors for the transport and dispersion of pollutants, including very mobile compounds These pollutants, which can be influenced by factors such as land use, rainfall intensity, and urban infrastructure, pose significant risks to both human and environmental health. Although several priority pollutants have traditionally been detected in urban stormwater, little is known about the presence of very mobile compounds that may threaten urban drinking water supplies and pose environmental risks to aquatic species. In this study, 131 urban rain and stormwater samples were collected from three districts of Barcelona (Spain) and analysed for 26 very mobile pollutants that are often overlooked in conventional monitoring efforts.
View Article and Find Full Text PDFThe accumulation process of pollutants in deposited particles of different sizes on different roads in Beijing, China.
Environ Geochem Health
December 2024
Key Laboratory of Urban Stormwater System and Water Environment, Ministry of Education, Beijing University of Civil Engineering and Architecture, Beijing, 100044, China.
Road-Deposited Sediments (RDS) samples were collected from four different roads in Beijing, and the distribution of pollutants in RDS with various particle sizes was compared. In this study, the cumulative mass of RDS exhibited a positive correlation with the number of dry days, and the RDS load below 75 μm was also influenced by road traffic volume. As traffic volume escalated, there was a corresponding increase in the load of these smaller RDS.
View Article and Find Full Text PDFInsights into the impact of 6PPD-Q and 6PPD on nitrogen metabolism and microbial community in the anammox system.
Environ Res
February 2025
School of Environment and Energy, South China University of Technology, Guangzhou, 510006, PR China.
N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD) is an antioxidant commonly used in tire manufacturing, and its release into the environment has significantly increased due to rapid urbanization. When subjected to ozonation, 6PPD converts into the harmful pollutant 6PPD quinone (6PPDQ). These substances enter wastewater treatment plants (WWTPs) via stormwater runoff and pipelines, posing significant risks to the functional microorganisms.
View Article and Find Full Text PDFA dataset of µCT images of small samples of constructed Technosol from bioretention cells.
Data Brief
December 2024
Czech Technical University in Prague, Faculty of Civil Engineering, Prague 166 29, Czech Republic.
The dataset represents micro computed tomography (µCT) images of undisturbed samples of constructed Technosol, obtained by sampling from the top layer of the biofilter in two bioretention cells. A bioretention cell is a stormwater management system designed to collect and temporarily retain stormwater runoff and treat it by filtering it through a soil media called a biofilter. Soil samples were collected at 7, 12, 18, 23, and 31 months after the establishment of bioretention cells.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!