A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted -type dihydride platinum(II) structure.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9367266 | PMC |
| http://dx.doi.org/10.1039/d2cc03089f | DOI Listing |
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