An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C-H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on the use of [Cu(bcp)DPEPhos]PF as the photoredox catalyst in the presence of potassium acetate and smoothly operates at room temperature.
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| http://dx.doi.org/10.1039/d2cc02146c | DOI Listing |
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