The interfacial modification of basalt-fiber-reinforced polymer (BFRP) composites is an essential research field and many techniques have been developed to improve the adhesion between basalt fiber (BF) and the matrix. However, most studies were based on the matrixes of general plastics and epoxy resins. In this work, five different chain structures of thermoplastic sizing agents were used to improve the interfacial properties of unidirectional BF-reinforced soluble and high-temperature-resistant poly(phthalazinone ether nitrile ketone) (BF/PPENK) composites. DMA results showed that the poly(ether nitrile) (PEN)-sized BF/PPENK (BF-PEN/PPENK) composite exhibited the optimal interfacial performance, with a storage modulus (') and glass transition temperature () up to 50 GPa and 288 °C, respectively. Moreover, the tensile strength, compressive strength, flexural strength, and interlaminar shear strength of the BF-PEN/PPENK composite reached 778 MPa, 600 MPa, 1115 MPa and 57 MPa, respectively, and increased by 42%, 49%, 20% and 30% compared with the desized BF/PPENK composite. This study provides some suggestions for the design of sizing agents to modify the interface of BF and high-performance thermoplastic resin.
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http://dx.doi.org/10.3390/polym14142947 | DOI Listing |
Mol Biol Rep
January 2025
Pediatric Cell, and Gene Therapy Research Center Gene, Cell and Tissue Research Institute, Tehran University of Medical Sciences, Tehran, Iran.
Bone serves as a fundamental structural component in the body, playing pivotal roles in support, protection, mineral supply, and hormonal regulation. However, critical-sized bone injuries have become increasingly prevalent, necessitating extensive medical interventions due to limitations in the body's capacity for self-repair. Traditional approaches, such as autografts, allografts, and xenografts, have yielded unsatisfactory results.
View Article and Find Full Text PDFInt J Mol Sci
January 2025
Centro de Investigación y Desarrollo de Nanomedicinas (CIDeN), Departamento de Ciencia y Tecnología, Universidad Nacional de Quilmes, Roque Sáenz Peña 352, B1876 Bernal, Argentina.
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View Article and Find Full Text PDFMaterials (Basel)
January 2025
Faculty of Mechanical Engineering, Institute of Mechanical Technology, Poznan University of Technology, Piotrowo 3, 60-695 Poznan, Poland.
Lubrication is a critical aspect of the metal forming process and it is strongly influenced by the surface texture of the tool-forming surfaces. This study is focused on determining the effect of surface finish and heat treatment on wettability involving commonly used lubrication agents. Three different finishing states are evaluated (as-ground, as-polished and as-nitrided).
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Mechanical, Chemical, and Materials Engineering, University of Cagliari, Via Marengo 2, 09123 Cagliari, CA, Italy.
Starch is among the most abundant natural compounds in nature after cellulose. Studies have shown that the structure and functions of starch differ extensively across and among botanical types, isolation procedures, and climate factors, resulting in starch with significant variations in its chemical, physical, morphological, thermal, and functional characteristics. To enhance its beneficial properties and address inherent limitations, starch is modified through various techniques, resulting in significant alterations to its chemical and physical characteristics.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, China.
Bead-foaming technology effectively addresses production cycles, polymerization control, and cellular structure defects in conventional bulk foaming, especially in high-performance PMI foams. In this work, highly expandable PMI beads were synthesized based on the aqueous suspension polymerization of methacrylic acid-methacrylonitrile-tert-butyl methacrylate (MAA-MAN-tBMA) copolymers. The suspension polymerization was stabilized by reducing the solubility of MAA by the salting-out effect and replacing formamide (a common PMI foaming agent) with tBMA.
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