Global minima (CBe and NBe) with planar tetracoordinate carbon and nitrogen atoms are stabilized by multicentric bonds. Their unusual anti-aromaticity is due to the strong localized Be-Be bonds preventing the full delocalization of the electrons in the CBe/NBe skeleton. These binary mono-anions are expected to be experimentally realized in the gas phase.
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| http://dx.doi.org/10.1039/d2cp01496c | DOI Listing |
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