The monoclinic wolframite-phase structure of ZnWO materials has been frequently synthesised, characterised, and applied in optical fibres, environmental decontamination, electrochemistry, photonics, catalysis, and not limited to magnetic applications. However, the problems of crystal growth conditions and mechanisms, growth, the crystal quality, stability, and the role of synthesis parameters of ZnWO nanoparticles remain a challenge limiting its commercial applications. This review presents recent advances of ZnWO as an advanced multi-functional material for Industrial wastewater treatment. The review also examines the influence of the synthesis parameters on the properties of ZnWO and provides insight into new perspectives on ZnWO-based photocatalyst. Many researches have shown significant improvement in the efficiency of ZnWO by mixing with polymers and doping with metals, nonmetals, and other nanoparticles. The review also provides information on the mechanism of doping ZnWO with metals, non-metals, metalloids, metals oxides, and polymers based on different synthesis methods for bandgap reduction and extension of its photocatalytic activity to the visible region. The doped ZnWO photocatalyst was a more effective and environmentally friendly material for removing organic and inorganic contaminants in industrial wastewater than ordinary ZnWO nanocrystalline under suitable growth conditions.
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http://dx.doi.org/10.1016/j.heliyon.2022.e09964 | DOI Listing |
J Colloid Interface Sci
October 2023
School of Environmental & Chemical Engineering, School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, PR China.
Zinc tungstate (ZnWO) shows great promise as an anode material for lithium-ion batteries (LIBs) owing to its reversible multi-electron redox reactions and high theoretical capacity. Nevertheless, the low conductivity and big strain during cycling can lead to the inferior electrochemical properties of the ZnWO anode, hindering its practical application. Herein, we report a novel composite with ZnWO/ZnO porous nanoplates in-situ constructed on reduced graphene oxide (rGO) by a metal-organic framework template strategy.
View Article and Find Full Text PDFNanoscale
November 2024
ChangZhou University, No. 21 Gehu Road, Wujin District, Changzhou 213164, China.
Phase change microcapsules (NePCMs) with high latent heat values, thermal conductivity and stability were synthesized by coating stearic acid (SA) phase change materials (PCMs) with zinc tungstate (ZnWO) as the shell material. The prepared ZnWO and microcapsule samples are characterized through various techniques, and their thermophysical properties under different core-shell ratios and emulsifiers are compared. The highest value that the phase transition enthalpy reaches is 83.
View Article and Find Full Text PDFDalton Trans
October 2024
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Environmentally Harmful Chemicals Analysis, Beijing University of Chemical Technology, Beijing 100029, China.
Photoelectrochemical water splitting represents a promising approach for directly converting solar energy into green hydrogen, offering a potential solution to the challenges of energy shortages and environmental pollution. In this work, a WO/ZnWO binary heterojunction was synthesised by a simple and effective one-step drop casting method to enhance the charge separation efficiency; ZnFe LDH was deposited on the surface of the heterojunction with the aim of accelerating water oxidation and synergising with the heterojunction to enhance the photoelectrochemical performance of the photoanode. The photocurrent density of the WO/ZnWO/ZnFe LDH electrode can reach 2.
View Article and Find Full Text PDFSensors (Basel)
August 2024
State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China.
Surface engineering techniques can be used to develop high-performance gas sensing materials and advance the development of sensors. In this study, we improved the gas sensing performance of two-dimensional (2D) WO nanoplates by combining surface Zn modification and the in situ formation of ZnWO/WO heterojunctions. Introducing Zn atoms by surface modification can reconstruct the atomic surface of 2D WO nanoplates, creating additional active sites.
View Article and Find Full Text PDFDalton Trans
September 2024
School of Materials Science and Engineering, Liaoning University of Technology, Jinzhou, 121001, PR China.
ZnWO@NiCoO core-shell nanosheet array composites are synthesized on nickel foam a two-step hydrothermal method. The optimal conditions, including a Ni(NO)·6HO to Co(NO)·6HO molar ratio of 2 : 1, 12 hours reaction time, and 120 °C temperature, yield a specific capacitance of 875 C g at 1 A g. The electrode also maintains 81.
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