We present a new velocity map imaging instrument for studying molecular beam surface scattering in a near-ambient pressure (NAP-VMI) environment. The instrument offers the possibility to study chemical reaction dynamics and kinetics where higher pressures are either desired or unavoidable, adding a new tool to help close the "pressure gap" between surface science and applied catalysis. NAP-VMI conditions are created by two sets of ion optics that guide ions through an aperture and map their velocities. The aperture separates the high pressure ionization region and maintains the necessary vacuum in the detector region. The performance of the NAP-VMI is demonstrated with results from NO photodissociation and N scattering from a Pd(110) surface, which are compared under vacuum and at near-ambient pressure (1 × 10 mbar). NAP-VMI has the potential to be applied to, and useful for, a broader range of experiments, including photoelectron spectroscopy and scattering with liquid microjets.
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http://dx.doi.org/10.1063/5.0098495 | DOI Listing |
Molecules
December 2024
School of Physics and Electronic Science, Zunyi Normal University, Zunyi 563006, China.
The geometrical structure, stability, electronic properties, and hydrogen storage capabilities of a titanium-doped B cluster was calculated using density functional theory computations. The results show that the TiB cluster is predicted to be stable under near-ambient conditions based on an ab initio molecular dynamic simulation. The transition state analysis found that the H molecule can dissociate on the TIB cluster surface to form a hydride cluster.
View Article and Find Full Text PDFACS Sens
December 2024
Material Analysis and Research Laboratory, Department of Physics, NSUT, Dwarka Sec-3, New Delhi 110078, India.
This work presents a room-temperature (RT) NO gas sensor based on cotton-modified LaFeO (CLFO) combined with MXene. LaFeO (LFO), CLFO, and CLFO/MXene composites were synthesized via a hydrothermal method. The fabricated sensor, utilizing MXene/CLFO, exhibits a p-type behavior and fully recoverable sensing capabilities for low concentrations of NO, achieving a higher response of 14.
View Article and Find Full Text PDFJ Am Chem Soc
November 2024
College of Energy, Xiamen University, Xiamen 361005, China.
The application of perovskite oxide for high-temperature electrocatalysis is hindered by its limited activity. Exsolution is a smart strategy that allows the enrichment of the perovskite's surface with highly reactive phases, yielding heteroboundaries. However, the identification of the exact catalytic role of this complex architecture is still elusive.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
Institute of High Pressure Physics, School of Physical Scientific and Technology, Ningbo University, Ningbo, 315211, People's Republic of China.
The pursuit of room-temperature superconductivity at an accessible synthetic pressure has been a long-held dream for both theoretical and experimental physicists. Recently, a controversial report by Dasenbrock-Gammon et al. claims that the nitrogen-doped lutetium trihydride exhibits room-temperature superconductivity at near-ambient pressure.
View Article and Find Full Text PDFSmall
November 2024
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China.
As a newly discovered Janus van der Waals (vdW) material, semiconducting NbSeI offers several notable advantages, including spontaneous out-of-plane polarization, facile exfoliation to the monolayer limit, and significant out-of-plane emission dipole in second harmonic generation. These properties make it a promising candidate for piezoelectric and piezophototronic applications in highly efficient energy conversion. However, NbSeI is prone to oxidation when exposed to oxygen, which can severely limit the exploration and utilization of these intriguing physical properties.
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