Nanocellulose has undergone substantial development as a high value-added cellulose product with broad applications. Dried products are advantageous to decrease transportation costs. However, dried nanocellulose has redispersion challenges when rewetting. In this work, drying techniques, factors affecting redispersibility, and strategies improving the nanocellulose redispersibility are comprehensively reviewed. Hydrogen bonds of nanocellulose are unavoidably developed during drying, leading to inferior redispersibility of dried nanocellulose, even hornification. Drying processes of nanocellulose are discussed first. Then, factors affecting redispersibility are discussed. Following that, strategies improving the nanocellulose redispersibility are analyzed and their advantages and disadvantages are highlighted. Surface charge modification and steric hindrance concept are two main pathways to overcome the redispersion challenge, which are mainly carried out by chemical modification, additive incorporation and non-cellulosic component preservation. Despite several advancements having been achieved, new approaches for enhancing the nanocellulose redispersibility are still required to promote the industrial-scale applications of nanocellulose in various domains.
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http://dx.doi.org/10.1016/j.carbpol.2022.119830 | DOI Listing |
Int J Biol Macromol
December 2024
Department of Agricultural Engineering, College of Engineering, China Agricultural University, Beijing 100083, China.
This study aims to explore the redispersibility of dehydrated nanocellulose with p-toluenesulfonic acid (p-TsOH) fractionated lignin as an eco-friendly and cost-effective capping agent, to cope with the challenge of irreversible agglomeration and thus loss of nanoscale of nanocellulose upon dehydration. The intermixing of nanocellulose and p-TsOH fractionated lignin was achieved using an aqueous ethanol solution as the medium and films of lignin-blending cellulose nanofibers (L + CNF) with excellent redispersing properties were obtained after facile air-drying. With 0.
View Article and Find Full Text PDFBiomacromolecules
December 2024
Jiangsu Co-Innovation Center for Efficient Processing and Utilization of Forest Resources and International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037, China.
Int J Mol Sci
August 2024
Department of Chemistry, Faculty of Science, Assiut University, Assiut 71516, Egypt.
Cellulose in the nano regime, defined as nanocellulose, has been intensively used for water treatment. Nanocellulose can be produced in various forms, including colloidal, water redispersible powders, films, membranes, papers, hydrogels/aerogels, and three-dimensional (3D) objects. They were reported for the removal of water contaminants, e.
View Article and Find Full Text PDFCarbohydr Polym
September 2024
SANKEN (The Institute of Scientific and Industrial Research), Osaka University, Ibaraki, Osaka 567-0047, Japan.
Dehydration of a cellulose nanofiber (CNF)/water dispersion requires large amounts of energy and time due to the high hydrophilicities and high specific surface areas of the CNFs. Various dehydration methods have been proposed for CNF/water dispersions; however, an efficient dehydration method for individually dispersed CNFs is needed. Here, electrodeposition of CNFs was evaluated as a dehydration method.
View Article and Find Full Text PDFCarbohydr Polym
June 2024
Department of Agriculture, Forestry and Bioresources, College of Agriculture & Life Sciences, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea; Research Institute of Agriculture and Life Sciences, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea. Electronic address:
Nanocellulose, owing to its environmentally friendly and unique attributes, is gaining traction in various industries. However, commercialization of nanocellulose faces challenges due to structural alterations during drying process, leading to irreversible aggregation. This study, inspired by wood's natural structure, introduces a cellulose nanofibril (CNF) drying system using hemicellulose hydrolysate (HH) as a capping agent.
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