We perform magnetotransport experiments on VI multilayers to investigate the relation between ferromagnetism in bulk and in exfoliated layers. The magnetoconductance measured on field-effect transistors and tunnel barriers shows that the Curie temperature of exfoliated multilayers is = 57 K, larger than in bulk ( = 50 K). Below ≈ 40 K, we observe an unusual evolution of the tunneling magnetoconductance, analogous to the phenomenology observed in bulk. Comparing the magnetoconductance measured for fields applied in- or out-of-plane corroborates the analogy, allows us to determine that the orientation of the eas-axis in multilayers is similar to that in bulk, and suggests that the in-plane component of the magnetization points in different directions in different layers. Besides establishing that the magnetic state of bulk and multilayers are similar, our experiments illustrate the complementarity of magnetotransport and magneto-optical measurements to probe magnetism in 2D materials.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acs.nanolett.2c01361 | DOI Listing |
NPJ 2D Mater Appl
January 2025
School of Physics, CRANN & AMBER Research Centres, Trinity College Dublin, Dublin, Ireland.
Thin films fabricated from solution-processed graphene nanosheets are of considerable technological interest for a wide variety of applications, such as transparent conductors, supercapacitors, and memristors. However, very thin printed films tend to have low conductivity compared to thicker ones. In this work, we demonstrate a simple layer-by-layer deposition method which yields thin films of highly-aligned, electrochemically-exfoliated graphene which have low roughness and nanometer-scale thickness control.
View Article and Find Full Text PDFSci Rep
January 2025
Centre for Advanced 2D Materials, National University of Singapore, Singapore, 117546, Singapore.
Kaolinite is a single 2D layer of kaolin or metakaolin (MK), common clays that can be characterized as layered 3D materials. We show that because of its chemical composition, kaolinite can be converted into an amorphous 3D material by chemical means. This dimensional transformation is possible due to the large surface to volume ratio and chemical reactivity of kaolinite.
View Article and Find Full Text PDFMolecules
December 2024
College of Mechanical and Electronic Engineering, Tarim University, Alar 843300, China.
Mater Horiz
January 2025
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, 441-8580, Aichi, Japan.
Photoelectrochemical (PEC) water splitting has attracted significant interest as a promising approach for producing clean and sustainable hydrogen fuel. An efficient photoanode is critical for enhancing PEC water splitting. Bismuth vanadate (BiVO) is a widely recognized photoanode for PEC applications due to its visible light absorption, suitable valence band position for water oxidation, and outstanding potential for modifications.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Eberhard Karls Universität Tübingen: Eberhard Karls Universitat Tubingen, Institut für Organische Chemie, Auf der Morgenstelle 18, 72076, Tübingen, GERMANY.
The direct incorporation of borondipyrromethene (BODIPY) subunits into the structural backbone of covalent organic frameworks (COFs) gives facile access to porous photosensitizers but is still a challenging task. Here, we introduce β‑ketoenamine-linked BDP‑TFP‑COF, which crystallizes in AA‑stacking mode with hcb topology. A comprehensive characterization reveals high crystallinity and enhanced stability in a variety of solvents, excellent mesoporosity (SABET = 1042 m2 g-1), broad light absorption in the visible region, and red emission upon the exfoliation of few-layer COF nanosheets.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!