Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P) using a cheap, commercially-available distannane, (BuSn), and anthraquinone as a simple photocatalyst. Subsequent 'one pot' transformation of the resulting stannylated monophosphine intermediate (BuSn)P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.
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| http://dx.doi.org/10.1039/d2cc03474c | DOI Listing |
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Photocatalytic stannylation of white phosphorus.
Chem Commun (Camb)
August 2022
University of Oxford, Department of Chemistry, OX1 3TA, Oxford, UK.
Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P) using a cheap, commercially-available distannane, (BuSn), and anthraquinone as a simple photocatalyst. Subsequent 'one pot' transformation of the resulting stannylated monophosphine intermediate (BuSn)P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.
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