The well-defined Pd(I) metalloradical [Pd(PBu)] reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PBu)(μ-I)] and phosphonium salts. Pd(II) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.
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| http://dx.doi.org/10.1039/d2dt02152h | DOI Listing |
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