Assessment of the Crystallization Process of CaO-AlO-SiO Glass Probed with Tb Luminescence.

Inorg Chem

Department of Material Science and Technology, Faculty of Advanced Engineering, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan.

Published: July 2022

The ratio of the intensity of Tb fluorescence at 543 nm because of an electric dipole transition (D-F) relative to that at 437 nm due to a magnetic dipole transition (D-F) was determined to be proportional to the amount of metastable CaAlSiO crystals precipitated in CaO-AlO-SiO glass. The present results indicate that Tb luminescence can be used as a probe to evaluate the crystallization of glass.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9326970PMC
http://dx.doi.org/10.1021/acs.inorgchem.2c01950DOI Listing

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