The effects of natural weathering ages on mineralogical, physical, and chemical properties of stacking molybdenum tailings.

This study investigated the influence of natural weathering on the mineralogical, physical, and chemical properties of molybdenum tailings from Shaanxi Province, China, stored at different stacking ages. The results showed that the mineralogical and chemical compositions of the molybdenum tailings remained stable after stacking for different years. The analysis of bulk density, porosity, field moisture capacity, and aggregate characteristics indicated that the physical structure of the molybdenum tailings was similar to a nearby soil with increasing stacking age in spite of a time-consuming process. In addition, 10 years of the natural weathering process resulted in the formation of more aggregates with the surface of microaggregates roughened, and displayed more debris and fine particles than stocking for 1 year. The findings showed that the bulk density of molybdenum tailings reduced from 1.45 to 1.42 g/cm after 10 years of storage, while its porosity rose from 46.5 to 49.4%. The fraction of large aggregate (> 0.25 mm) and mean weight diameter increased from 7.91 to 42.07% and from 0.1482 to 0.1864 mm, respectively, which demonstrated that the natural weathering significantly improved the physical properties of the aggregate and enhanced the structural stability. Thus, natural weathering provides an ecological basis for restoring and reconstructing the soil ecosystem in molybdenum tailings. The results confirmed that long-term deposition can improve the soil structure of tailings, which provides a reference for further research on restoring and reconstructing the soil ecosystem in molybdenum tailings.