AI Article Synopsis
- The SuFEx reaction involves sulfonimidoyl fluorides and phenols, producing sulfonimidates that exhibit dynamic covalent chemistry.
- This reaction is notable for being enantiospecific, quick (completing in minutes at room temperature), and yielding high outputs.
- It has potential applications in asymmetric synthesis and sustainable polymer production, highlighting its versatility within the realm of SuFEx and similar click chemistries.
Article Abstract
The products of the SuFEx reaction between sulfonimidoyl fluorides and phenols, sulfonimidates, are shown to display dynamic covalent chemistry with other phenols. This reaction was shown to be enantiospecific, finished in minutes at room temperature in high yields, and useful for both asymmetric synthesis and sustainable polymer production. Its wide scope further extends the usefulness of SuFEx and related click chemistries.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540147 | PMC |
| http://dx.doi.org/10.1002/anie.202207456 | DOI Listing |
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