The concept of green site remediation calls for a model that can consider environmental impacts in the selection of site remediation alternatives. In this study, an integrated life cycle assessment (LCA)-fuzzy synthetic evaluation (FSE) model is developed to help practitioners select the optimal site remediation plan by incorporating life cycle impacts into the comprehensive suitability evaluation. The LCA module quantifies environmental and economic impacts using ReCiPe and Input-Output LCA methods, respectively. The impacts are evaluated along with other suitability considerations, presented in 32 indicators under ten criteria, by practitioners through a questionnaire survey. FSE is used to process the collected subjective judgments and generate a suitability index for informed selection. The integrated model is applied to a case study of an abandoned chemical industrial site contaminated by various organic chemicals and mercury. Four remediation alternatives, designed as the combined uses of ex-situ thermal desorption, in-situ thermal desorption, and in-situ containment, are evaluated. The LCA results show that the alternative with extensive use (treating 93.8 % of the contaminated soil) of in-situ thermal desorption is associated with the highest environmental and economic impacts, followed by the alternative with less extensive use (6.2 %) of in-situ thermal desorption. The FSE results show that the economic, technical, and environmental impact considerations are the top three important criteria. The integrated LCA-FSE results indicate that the alternative with mixed use of ex-situ thermal desorption and in-situ containment could be the optimal plan. Excluding LCA results could alter the suitability ranks of the alternatives.
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http://dx.doi.org/10.1016/j.scitotenv.2022.157211 | DOI Listing |
Small Methods
January 2025
Department of Gastroenterology and Hepatology, Zhongshan Hospital, Department of Chemistry, Department of Institutes of Biomedical Sciences, Fudan University, Shanghai, 200032, China.
The rarity and heterogeneity of liposarcomas (LPS) pose significant challenges in their diagnosis and management. In this work, a series of metal-organic frameworks (MOFs) engineering is designed and implemented. Through comprehensive characterization and performance evaluations, such as stability, thermal-driven desorption efficiency, as well as energy- and charge-transfer capacity, the engineering of group IV bimetallic MOFs emerges as particularly noteworthy.
View Article and Find Full Text PDFEnviron Res
January 2025
Key Laboratory of Environmental Nanotechnology and Health Effects, State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China. Electronic address:
Hexachlorobutadiene (HCBD), as an emerging persistent organic pollutant, poses a pressing global environmental issue concerning its reduction and control. However, the lack of systematic studies on the sources and occurrence of HCBD hinders the development of effective disposal technologies. This study addresses HCBD prevention and treatment from multiple perspectives, including source emissions, environmental contamination distribution, and control technologies.
View Article and Find Full Text PDFEnviron Monit Assess
January 2025
Institut de Recherche Robert-Sauvé en Santé Et en Sécurité du Travail (IRSST), Montréal, Québec, Canada.
Langmuir
January 2025
Key Laboratory of Insitu Property improving Mining of Ministry of Education, Taiyuan University of Technology, No,18 Xinkuangyuan Road, Wanbailin District, Taiyuan, Shanxi 030024, P. R. China.
In terms of the phenomenon of nonuniformity adsorption energy between methane and a natural heterogeneous coal surface, a heterogeneous potential well model is established in this study based on adsorption science and molecular dynamics theories. This model describes the methane adsorption positions in coal pores as a three-dimensional space composed of adsorption equipotential surfaces with varying depths of potential well, which emphasizes the heterogeneous distribution of methane adsorption potential well depths in coal and accurately describes the spatial distribution and energy states of methane molecules during methane adsorption and desorption in naturally heterogeneous coal. By taking the residual sum of squares (RSS) and Pearson correlation coefficient as indicators, the fitting accuracies of the Langmuir model and the heterogeneous potential well model for isothermal adsorption and desorption curves are compared so that the superiority of the heterogeneous potential well model in describing the adsorption and desorption of methane in natural coal is confirmed.
View Article and Find Full Text PDFAnalyst
January 2025
School of Mechanical and Electrical Engineering, Soochow University, Suzhou, 215021, China.
A portable gas chromatograph-mass spectrometer (GC-MS) is an effective instrument for rapid on-site detection of volatile organic compounds (VOCs). Current instruments typically adsorb samples at ambient temperature, challenging the detection of low-boiling VOCs. In this study, a low-temperature adsorption thermal desorption method is proposed for sample enrichment in a portable GC-MS.
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