Seven commercial gluten-free (rice, oat, sorghum, foxtail millet, amaranth, quinoa, and buckwheat) flours were investigated in this study from the point of view of thermo-mechanical properties and solvent retention capacity (SRC). Each flour was used to prepare doughs with specific water absorption (WA) to get a consistency of 1.1 Nm (WA1) and doughs with WA2 levels higher than 85% to ensure a sufficient amount of water in the system for allowing the hydration of all components of the flours. Different correlations were established between proteins, ash, pentosans, damaged starch, and amylose contents on the one hand, and the capacity of the flour samples to retain different solvents such as sucrose, sodium carbonate and CaCl on the other hand. Although no significant correlation was found between the protein content of the flours and lactic acid-SRC, the mechanical weakening of the protein was significantly correlated with lactic acid-SRC for both tested WA levels. The doughs with WA1 had higher starch gelatinization and hot gel stability values compared to the corresponding dough systems with a higher water amount. Moreover, lower starch retrogradation and setback torques were obtained in the case of the dough prepared with higher amounts of water.
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http://dx.doi.org/10.3390/foods11131857 | DOI Listing |
Chemistry
January 2025
Friedrich-Schiller-Universität Jena: Friedrich-Schiller-Universitat Jena, Laboratory of Organic and Macromolecular Chemistry, GERMANY.
This current study focusses on the investigation of the self-healing abilities of metallopolymers containing different kinds of metal complexes, which were processed by direct digital light processing (DLP) based three-dimensional (3D) printing. For this purpose, 2‑phenoxyethyl acrylate is mixed with ligand-containing monomers either based on triphenylmethyl(trt)-histidine or terpyridine, respectively. Either zinc(II) or nickel(II) salts are successfully applied for a complexation of the ligand monomers in solution and, subsequently, photopolymerization is performed.
View Article and Find Full Text PDFACS Omega
January 2025
Swedish Centre for Resource Recovery, Faculty of Textiles, Engineering and Business, University of Borås, 501 90 Boras, Sweden.
This study investigates the morphology and thermo-mechanical properties of cross-linked polyethylene (PEX) pipes for potential use in high-temperature borehole thermal energy storage systems. Particular attention is given to a novel type of PEX pipe produced through photoinitiated cross-linking (PEX-e). Two formulations, PEX-e1 and PEX-e2, were analyzed and compared to peroxide-cross-linked polyethylene (PEX-a) and non-cross-linked bimodal polyethylene (PE100) pipes.
View Article and Find Full Text PDFInt J Pharm
January 2025
Sezione di Tecnologia e Legislazione Farmaceutiche "Maria Edvige Sangalli", Dipartimento di Scienze Farmaceutiche, Università degli Studi di Milano, via Giuseppe Colombo 71, 20133, Milano, Italy.
Targeting the development of 3D printed reservoir-like vaginal rings (VRs) intended to fulfill the needs of precision medicine, prototypes ensuring prolonged release of metronidazole (MTZ) were preliminary manufactured and tested. Indeed, this drug represents the first-line therapy against bacterial vaginosis, which would especially benefit from convenient as well as easy dose adjustment and from more than 48 h continuous release, thus avoiding barely tolerated and repeated administrations. Starting from a soft thermoplastic elastomer (TPE), hollow ring structures were successfully printed at 190 °C and then extemporaneously filled with drug-loaded, in-situ-crosslinking hydrogel formulations based on alginate (ALG).
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Food Packaging Technology Department, CSIR-Central Food Technological Research Institute, Mysuru, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, Uttar Pradesh 201002, India. Electronic address:
Multifunctional PLA films were fabricated through the solution casting method by incorporating cardanol oil (CA) and amine-functionalized graphene (AFG). The effect of the CA, and AFG on the structural, mechanical, thermal, thermo-mechanical and antioxidant properties of PLA films were investigated. FTIR analysis of PLA-CA films showed distinct peak positions at 1590 cm corresponding to the aromatic CC bonds of CA, showing that CA is compatible with the PLA.
View Article and Find Full Text PDFSci Rep
January 2025
Mechanical Engineering, Stanford University, Stanford, CA, 94305, USA.
Triply periodic minimal surface (TPMS) metamaterials show promise for thermal management systems but are challenging to integrate into existing packaging with strict mechanical requirements. Composite TPMS lattices may offer more control over thermal and mechanical properties through material and geometric tuning. Here, we fabricate copper-plated, 3D-printed triply periodic minimal surface primitive lattices and evaluate their suitability for battery thermal management systems.
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