Direct phosphorylation of benzylic C-H bonds was achieved in a biphasic system under transition metal-free conditions. A selective radical/radical spC-H/P(O)-H cross coupling was proposed, and various substituted toluenes were applicable. The transformation provided a promising method for constructing spC-P bonds.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9227801 | PMC |
| http://dx.doi.org/10.1039/d2ra02812c | DOI Listing |
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