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Article Abstract
The reaction of cyclopropenes with compounds containing Mg-Mg bonds is reported. 1,2-Dimagnesiation occurs exclusively by -addition to the least hindered face of the alkene forming a single diastereomeric product. DFT calculations support a concerted and stereoselective mechanism. These findings shed new light on the stereochemistry of reactions involving magnesium reagents.
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| http://dx.doi.org/10.1039/d2cc02931f | DOI Listing |
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