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<PubmedArticle><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">35788228</PMID><DateRevised><Year>2022</Year><Month>07</Month><Day>21</Day></DateRevised><Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">1364-548X</ISSN><JournalIssue CitedMedium="Internet"><Volume>58</Volume><Issue>59</Issue><PubDate><Year>2022</Year><Month>Jul</Month><Day>21</Day></PubDate></JournalIssue><Title>Chemical communications (Cambridge, England)</Title><ISOAbbreviation>Chem Commun (Camb)</ISOAbbreviation></Journal><ArticleTitle>Solvent-free Zn (NSNO) complex-catalysed dihydroboration of nitriles.</ArticleTitle><Pagination><StartPage>8266</StartPage><EndPage>8269</EndPage><MedlinePgn>8266-8269</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/d2cc03517k</ELocationID><Abstract><AbstractText>N-donors are the most commonly employed Lewis bases in ligand-assisted catalysis. A dimeric zinc complex (Zn-1) employing a tetradentate pyridine-thioether-anilido-aryloxide NSNO ligand (L) effects the quantitative conversion of nitriles to the corresponding double hydroborated products at 1 mol% catalyst loading. Variable Time Normalization Analysis kinetic studies showed a first-order dependence with respect to the nitrile, pinacolborane and zinc and clear evidence for catalyst deactivation. A plausible ligand-assisted reaction pathway involves B-H bond activation by the aryloxide (<i>vs.</i> anilido) donor.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Ataie</LastName><ForeName>Saeed</ForeName><Initials>S</Initials><Identifier Source="ORCID">0000-0001-8247-1321</Identifier><AffiliationInfo><Affiliation>Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada. rbaker@uottawa.ca.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Ovens</LastName><ForeName>Jeffrey S</ForeName><Initials>JS</Initials><AffiliationInfo><Affiliation>Faculty of Science, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Tom Baker</LastName><ForeName>R</ForeName><Initials>R</Initials><Identifier Source="ORCID">0000-0002-1133-7149</Identifier><AffiliationInfo><Affiliation>Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada. rbaker@uottawa.ca.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2022</Year><Month>07</Month><Day>21</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Chem Commun (Camb)</MedlineTA><NlmUniqueID>9610838</NlmUniqueID><ISSNLinking>1359-7345</ISSNLinking></MedlineJournalInfo><CitationSubset>IM</CitationSubset></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2022</Year><Month>7</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2022</Year><Month>7</Month><Day>6</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2022</Year><Month>7</Month><Day>5</Day><Hour>18</Hour><Minute>19</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">35788228</ArticleId><ArticleId IdType="doi">10.1039/d2cc03517k</ArticleId></ArticleIdList></PubmedData></PubmedArticle></PubmedArticleSet>