AI Article Synopsis
- - The study focuses on creating heterochiral porous organic cages (HPOC-1) using specific enantiomers of cyclohexanediamine and binaphthol, emphasizing the significance of chiral recognition in both biological processes and supramolecular material fabrication.
- - The assembly of HPOC-1 was monitored through nuclear magnetic resonance and luminescence spectroscopy, demonstrating that the cages were formed through enantioselective interactions between the chiral components.
- - HPOC-1 displays notable properties such as circularly polarized luminescence and the ability to selectively recognize chiral substrates, with theoretical simulations helping to explain its enantioselective assembly and recognition mechanisms.
Article Abstract
Chiral recognition and discrimination is not only of significance in biological processes but also a powerful method to fabricate functional supramolecular materials. Herein, a pair of heterochiral porous organic cages (HPOC-1), out of four possible enantiomeric products, with mirror stereoisomeric crystal structures were cleanly prepared by condensation occurring in the exclusive combination of cyclohexanediamine and binaphthol-based tetraaldehyde enantiomers. Nuclear magnetic resonance and luminescence spectroscopy have been employed to monitor the assembly process of HPOC-1, revealing the clean formation of heterochiral organic cages due to the enantioselective recognition of (,)-binaphthol towards (,)-cyclohexanediamine derivatives and . Interestingly, HPOC-1 exhibits circularly polarized luminescence and enantioselective recognition of chiral substrates according to the circular dichroism spectral change. Theoretical simulations have been carried out, rationalizing both the enantioselective assembly and recognition of HPOC-1.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9200113 | PMC |
| http://dx.doi.org/10.1039/d2sc01876d | DOI Listing |
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