A ratio fluorescence sensor based on rhodamine B embedded metal-organic framework for glyphosate detection in agri-food products.

Food Chem

State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, Wuxi 214122, China. Electronic address:

Published: November 2022

Glyphosate, a broad-spectrum and high-efficiency herbicide, could accumulate in the human body through the consumption of agri-food products. Herein, a ratio fluorescence sensor based on rhodamine B-embedded amino-functionalized iron-based metal-organic framework (MOF, NH-MIL-88(Fe)@RhB) bonded with Cu was developed for rapid detection of glyphosate. The synthesized NH-MIL-88(Fe) was a biconical prism and had a cavity for the embedding of RhB as a reference compound. In the presence of Cu, Lewis interactions with NH-MIL-88(Fe)@RhB cause the fluorescence signal to be turned off. When glyphosate was added, the signal was turned on due to chelation with Cu and hydrogen bonding interactions with NH-MIL-88(Fe)@RhB. Under optimal conditions, the developed sensor exhibited a linear range of 0.60-45 μmol L with a response time of less than 1 min. The sensor was applied in the analysis of agri-food products (tea, soybean, wheat, cucumber), with recoveries between 97.93% and 109.06%, indicating its promising application in agri-food safety.

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http://dx.doi.org/10.1016/j.foodchem.2022.133446DOI Listing

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