Fused filament fabrication (FFF) additive manufacturing technology has the advantages of being low cost, having a simple operation, using wide types of molding materials, and producing less pollution during the printing process. However, the mechanical properties of the molded sample are unsatisfactory due to the limited bonding force between the filaments during the forming process, which limits its further development and application in the engineering field. Herein, the hybrid additive manufacturing technology for heterogeneous materials based on the ultrasonic-assisted enhanced fused filament fabrication technology was proposed. The mechanism of ultrasonic vibration on the strengthening of FFF samples was explored. The influence mechanisms of bonding time and ultrasonic strengthening times, ultrasonic strengthening and static load compression on the strengthening of mechanical properties of the sample were investigated. The effects of the thickness and printing angle of the FFF samples on the ultrasonic-enhanced mechanical properties were explored. The tensile strength of the one-time ultrasonic-strengthened sample is up to 43.43 MPa, which is 16.12% higher than that of the original. The maximum bending strength of the four-time ultrasonic-strengthened sample is 73.38 MPa, which is 78.98% higher than that of the original. Ultrasonic strengthening not only re-fused the pores inside the sample, but also improved the bond strength between the rasters. With the increase in the thickness of the sample, the increase rate of ultrasonic to the strength of the sample decreased significantly. The effects of ultrasound on the interlayer adhesion of samples with various printing angles were different. Based on the systematic research on the influence mechanism of ultrasonic process parameters and molding process parameters on the strengthening of FFF, a molding method for additively manufacturing heterogeneous material parts while strengthening the mechanical properties of FFF samples was proposed, and the influence mechanisms of the molding process on the mechanical properties and shape memory properties of the sample were explored, which can broaden the application of FFF technology in the engineering field.
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http://dx.doi.org/10.3390/polym14122385 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Mechanical Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Hong Kong, SAR, China.
Advanced energetic composites possess promising properties and wide-ranging applications in explosives and propellants. Nonetheless, most metal-based energetic composites present significant challenges due to surface oxidation and low-pressure output. This study introduces a facile method to develop energetic composites Cutztr@AP through the intermolecular assembly of nitrogen-rich energetic coordination polymers and high-energy oxidant ammonium perchlorate (AP).
View Article and Find Full Text PDFClin Oral Investig
January 2025
Sir John Walsh Research Institute, Faculty of Dentistry, University of Otago, Dunedin, New Zealand.
Objectives: The aim of this systematic review was to assess the effect of DM (Type 1 and Type 2 Diabetes) and hyperglycaemia on the physical and mechanical properties of dentine which is critical for successful endodontic treatment.
Method: An electronic search of the following databases: PubMed, MEDLINE, Web of Science and the grey literature was performed up until July 2024. In vitro and in vivo studies on the effect of DM or hyperglycaemia on the mechanical and physical properties of dentine were included.
ACS Appl Mater Interfaces
January 2025
Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, Pennsylvania 16802, United States.
We study the Raman signature of stripe domains in monolayer WMoS alloys, characterized using experimental techniques and density functional theory (DFT) calculations. These stripe domains were found in star-shaped monolayer WS exhibiting a high concentration of molybdenum (Mo) atoms in its central region, and unique Raman peaks that were not previously reported. We attribute these peaks to the splitting of the original doubly degenerate E modes, arising from the lower symmetry of the W-Mo stripe domains.
View Article and Find Full Text PDFInvest Ophthalmol Vis Sci
January 2025
Department of Physics, Boise State University, Boise, Idaho, United States.
Purpose: To elucidate the mechanical properties of the bovine lens cortical membrane (CM), the nuclear membrane (NM) containing cholesterol bilayer domains (CBDs), and whole bovine lenses.
Methods: The total lipids (lipids plus cholesterol) from the cortex and nucleus of a single bovine lens were isolated using the monophasic methanol extraction method. Supported CMs and NMs were prepared from total lipids extracted from the cortex and nucleus, respectively, using a rapid solvent exchange method and probe-tip sonication, followed by the fusion of unilamellar vesicles on a flat, freshly cleaved mica surface.
ACS Macro Lett
January 2025
Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, China.
The microcapsule-containing self-reporting system has attracted attention for its excellent characteristics in visualizing microdamage. In this study, we developed self-reporting materials based on the formation of donor-acceptor Stenhouse adducts (DASA) from microcapsules containing Meldrum's acid furfural conjugate (MAFC). Under mechanical force, MAFC is released from broken microcapsules and forms highly colored DASA with secondary amines in the matrix to indicate the small cracks or deformations.
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