Three supramolecular bromostannates(IV) with "trapped" diiodine molecules, Cat{[SnBr](I)} (Cat = MeN (), 1-MePy () and 4-MePyH ()), were synthesized. In all cases, I linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that are narrow band gap semiconductors.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9229721 | PMC |
| http://dx.doi.org/10.3390/molecules27123859 | DOI Listing |
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