We report on shear-ordered polymer photonic crystals demonstrating intense structural color with a photonic bandgap at 270 nm. Our work examines this UV structural color, originating from a low refractive index contrast polymer composite system as a function of the viewing angle. We report extensive characterization of the angle-dependent nature of this color in the form of 'scattering cones', which showed strong reflectivity in the 275-315 nm range. The viewing range of the scattering was fully quantified for a number of planes and angles, and we additionally discuss the unique spectral anisotropy observed in these structures. Such films could serve as low-cost UV reflection coatings with applications in photovoltaics due to the fact of their non-photobleaching and robust mechanical behavior in addition to their favorable optical properties.
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http://dx.doi.org/10.3390/molecules27123774 | DOI Listing |
Mater Horiz
January 2025
School of Materials Science and Engineering, Peking University, Beijing 1008711, P. R. China.
Intelligent soft robots that integrate both structural color and controllable actuation ability have attracted substantial attention for constructing biomimetic systems, biomedical devices, and soft robotics. However, simultaneously endowing single-layer cholesteric liquid crystal elastomer (CLCE) soft actuators with reversible 3D deformability and vivid structural color changes is still challenging. Herein, a multi-responsive (force, heat and light) single-layer 3D deformable soft actuator with vivid structural color-changing ability is realized through the reduced graphene oxide (RGO) deposition-induced Janus structure of the CLCE using a precisely-controlled evaporation method.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Humboldt-Universität zu Berlin, Department of Chemistry, Laboratory of Organic Chemistry and Functional Materials, Brook-Taylor-Str. 2, 12489, Berlin, GERMANY.
Here we disclose that spiropyrans are able to undergo dynamic covalent exchange via their corresponding merocyanine isomers. In the latter, the indolinium moieties can be exchanged by a Michael-type addition-elimination sequence, in which a methylene indoline attacks a merocyanine and subsequently the initial indoline fragment is cleaved. The rate and position of the exchange equilibrium strongly depend on the reaction conditions as well as the substitution pattern on the methylene indoline fragments.
View Article and Find Full Text PDFFront Plant Sci
December 2024
Jiangxi Branch of China National Tobacco Corporation, Nanchang, China.
Due to the constraints of the tobacco leaf curing environment and computational resources, current image classification models struggle to balance recognition accuracy and computational efficiency, making practical deployment challenging. To address this issue, this study proposes the development of a lightweight classification network model for recognizing tobacco leaf curing stages (TCSRNet). Firstly, the model utilizes an Inception structure with parallel convolutional branches to capture features at different receptive fields, thereby better adapting to the appearance variations of tobacco leaves at different curing stages.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory, Jieyang 515200, China.
Optical physical unclonable functions (PUFs) are gaining attention as a robust security solution for identification in the expanding Internet of Things (IoT). To enhance the security and functionality of PUFs, integrating multiple optical responses─such as fluorescence and structural color─into a single system is essential. These diverse optical properties enable multilevel authentication, where different layers of security can be verified under varying light conditions, greatly reducing the risk of counterfeiting.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
College of Textiles & Clothing, Collaborative Innovation Center for Eco-Textiles of Shandong Province and the Ministry of Education, Laboratory for Manufacturing Low Carbon and Functionalized Textiles in the Universities of Shandong Province, Qingdao University, Qingdao 266071, China; Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing University, Shaoxing 312000, China. Electronic address:
Silk/polyamide fabric inherits the advantages of natural and synthetic fibers, making them remarkable in textile and garment field. However, the use of synthetic chemicals for color construction and functionalization of silk/polyamide fabrics is problematic because of their non-renewable resources and harmful effects on the environment. Furthermore, achieving even color construction of silk and polyamide fibers in one bath is challenging due to their significant differences in chemical structure and surface properties.
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