A simple method for preparing superconducting NbN thin films on flexible dielectric substrates with controllable thickness was developed. The structure and surface characteristics and superconducting properties of the flexible film were studied by X-ray diffraction (XRD), atomic force microscopy (AFM) and physical property measurement system (PPMS). We found that NbN films on the flexible substrate show certain preferred orientations through the self-buffering effect of the amorphous NbN layer. The zero resistance superconducting transition temperature (T) for 10 nm thick NbN films is 8.3 K, and the T for 30 nm thick NbN films in a magnetic field of 9 T remains above 7 K. This flexible film can be transferred to any substrate and adapted to different shape applications. It can also be further processed into single-layer or multilayer flexible superconducting devices.
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http://dx.doi.org/10.1038/s41598-022-14861-z | DOI Listing |
J Colloid Interface Sci
February 2025
Key Laboratory of Functional Materials and Applications of Fujian Province, School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, China. Electronic address:
Transition metal nitrides (TMNs) are promising electrode materials for supercapacitors because of their high electrical conductivity and chemical stability. The rational design and facile synthesis of TMNs electrode materials with a unique nanostructure are the key to develop high-performance supercapacitors. Herein, we propose a two-step, binder-free, and eco-friendly approach utilizing magnetron sputtering at an oblique angle deposition configuration to fabricate hierarchical Nb@NbN core-shell-like nanocolumns for supercapacitors.
View Article and Find Full Text PDFNano Lett
February 2024
Department of Materials Science and Engineering, National University of Singapore, Singapore 117575.
The rapid development of infrared spectroscopy, observational astronomy, and scanning near-field microscopy has been enabled by the emergence of sensitive mid- and far-infrared photodetectors. Superconducting hot-electron bolometers (HEBs), known for their exceptional signal-to-noise ratio and fast photoresponse, play a crucial role in these applications. While superconducting HEBs are traditionally crafted from sputtered thin films such as NbN, the potential of layered van der Waals (vdW) superconductors is untapped at THz frequencies.
View Article and Find Full Text PDFMaterials (Basel)
November 2023
Applied Materials Inc., Santa Clara, CA 95054, USA.
We report a milestone in achieving large-scale, ultrathin (~5 nm) superconducting NbN thin films on 300 mm Si wafers using a high-volume manufacturing (HVM) industrial physical vapor deposition (PVD) system. The NbN thin films possess remarkable structural uniformity and consistently high superconducting quality across the entire 300 mm Si wafer, by incorporating an AlN buffer layer. High-resolution X-ray diffraction and transmission electron microscopy analyses unveiled enhanced crystallinity of (111)-oriented δ-phase NbN with the AlN buffer layer.
View Article and Find Full Text PDFPhys Rev Lett
November 2023
Institute for Experimental and Applied Physics, University of Regensburg, D-93040 Regensburg, Germany.
We present a comprehensive investigation of the Berezinskii-Kosterlitz-Thouless transition in ultrathin strongly disordered NbN films. Measurements of resistance, current-voltage characteristics, and kinetic inductance on the very same device reveal a consistent picture of a sharp unbinding transition of vortex-antivortex pairs that fit standard renormalization group theory without extra assumptions in terms of inhomogeneity. Our experiments demonstrate that the previously observed broadening of the transition is not an intrinsic feature of strongly disordered superconductors and provide a clean starting point for the study of dynamical effects at the Berezinskii-Kosterlitz-Thouless transition.
View Article and Find Full Text PDFSci Rep
November 2023
Department of Experimental Physics, Faculty of Mathematics, Physics and Informatics, Comenius University Bratislava, 84248, Bratislava, Slovak Republic.
Magneto-transport characteristics of 2D and 3D superconducting layers, in particular, temperature and angular dependences of the upper critical field H, are usually considered to be fundamentally different. In the work, using non-local resistance measurements at temperatures near the normal-to-superconducting transition, we probed an effective dimensionality of nm-thick NbN films. It was found that in relatively thick NbN layers, the thicknesses of which varied from 50 to 100 nm, the temperature effect on H certainly pointed to the three-dimensionality of the samples, while the angular dependence of H revealed behavior typical for 2D samples.
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