We propose a minimalist phenomenological model for the 'interfacial water' phenomenon that occurs near hydrophilic polymeric surfaces. We achieve this by combining a Ginzburg-Landau approach with Maxwell's equations which leads us to a well-posed model providing a macroscopic interpretation of experimental observations. From the derived governing equations, we estimate the unknown parameters using experimental measurements from the literature. The resulting profiles of the polarization and electric potential show exponential decay near the surface, in qualitative agreement with experiments. Furthermore, the model's quantitative prediction of the electric potential at the hydrophilic surface is in excellent agreement with experiments. The proposed model is a first step towards a more complete parsimonious macroscopic model that will, for example, help to elucidate the effects of interfacial water on cells (e.g. neuronal excitability), the effects of infrared neural stimulation or the effects of drugs mediated by interfacial water.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1088/1361-648X/ac7b5d | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Responsive Surfactant-Driven Morphology Transformation of Block Copolymer Microparticles.
Chemistry
January 2025
Huazhong University of Science and Technology, 1037 Luoyu Road, 430074, Wuhan, CHINA.
Block copolymer (BCP) microparticles, which exhibit rapid change of morphology and physicochemical property in response to external stimuli, represent a promising avenue for the development of programmable smart materials. Among the methods available for generating BCP microparticles with adjustable morphologies, the confined assembly of BCPs within emulsions has emerged as a particularly facile and versatile approach. This review provides a comprehensive overview of the role of responsive surfactants in modulating interfacial interactions at the oil-water interface, which facilitates controlled BCP microparticle morphology.
View Article and Find Full Text PDFSelf-Assembly Strategy for Synthesis of WO@TCN Heterojunction: Efficient for Photocatalytic Degradation and Hydrogen Production via Water Splitting.
Molecules
January 2025
Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Herein, a WO@TCN photocatalyst was successfully synthesized using a self-assembly method, which demonstrated effectiveness in degrading organic dyestuffs and photocatalytic evolution of H. The synergistic effect between WO and TCN, along with the porous structure of TCN, facilitated the formation of a heterojunction that promoted the absorption of visible light, accelerated the interfacial charge transfer, and inhibited the recombination of photogenerated electron-hole pairs. This led to excellent photocatalytic performance of 3%WO@TCN in degrading TC and catalyzing H evolution from water splitting under visible-light irradiation.
View Article and Find Full Text PDFStudy of the Influence of Desert Sand-Mineral Admixture on the Abrasion Resistance of Concrete.
Materials (Basel)
January 2025
College of Water Conservancy & Architectural Engineering, Shihezi University, Shihezi 832000, China.
The incorporation of desert sand-mineral admixture improves the abrasion resistance of concrete. To prolong the service life of assembled concrete channels and mitigate the depletion of river sand resources, the effects of fly ash (FA), silica fume (SF), desert sand (DS), and basalt fiber (BF) on the mechanical properties and the abrasion resistance of concrete were examined, alongside an analysis of their microstructures to elucidate the underlying mechanisms of influence. The results indicated that the abrasion resistance strength of concrete mixed with 10% FA and 0.
View Article and Find Full Text PDFWhey Protein Hydrogels and Emulsion Gels with Anthocyanins and/or Goji Oil: Formation, Characterization and In Vitro Digestion Behavior.
Antioxidants (Basel)
January 2025
State Key Laboratory of Food Science and Resources, Jiangnan University, Wuxi 214122, China.
Whey protein isolate (WPI) has functional properties such as gelation and emulsification. Emulsion gels combine the benefits of both emulsions and hydrogels. In this study, WPI hydrogels and emulsion gels were developed with goji oil (GO) as the oil phase by the inclusion of blueberry extract (BE) in the protein matrix.
View Article and Find Full Text PDFA critical review on arsenic and antimony adsorption and transformation on mineral facets.
J Environ Sci (China)
July 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address:
Arsenic (As) and antimony (Sb), with analogy structure, belong to VA group in the periodic table and pose a great public concern due to their potential carcinogenicity. The speciation distribution, migration and transformation, enrichment and retention, as well as bioavailability and toxicity of As and Sb are influenced by several environmental processes on mineral surfaces, including adsorption/desorption, coordination/precipitation, and oxidation/reduction. These interfacial reactions are influenced by the crystal facet of minerals with different atomic and electronic structures.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!