The cluster [CoAs(CO)] was obtained by pyrolysis of [CoAs(CO)]. The metal cage features a closed-packed core inside a Co/As shell that progressively deforms from a cubic face-centered symmetry. The redox and acid-base reactivities were determined by cyclic voltammetry and spectrophotometric titrations. The calculated electron density revealed the shell-constrained distribution of the atomic charges, induced by the presence of arsenic.
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| http://dx.doi.org/10.1021/acs.inorgchem.2c00506 | DOI Listing |
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