Appropriate aggregation is needed for highly active Pt/AlO to enable hydrogenation of chlorinated nitrobenzene.

Chem Commun (Camb)

Key Lab of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.

Published: July 2022

The atomic dispersion of a noble metal with a reducible support has been reported to be beneficial for catalytic hydrogenation reactions. Conversely, we found that Pt particles (3-5 nm) could be obtained on the non-reducible support AlO by weakening the interaction between the metal and support using oleic acid, and the turnover frequency of catalyzing the hydrogenation of chlorinated nitrobenzene could reach 3700 h, which is three orders of magnitude higher than that of atomic platinum species.

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http://dx.doi.org/10.1039/d2cc00940dDOI Listing

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