Solar energy-facilitated materials are promising to solve energy problems by converting clean solar energy to thermal energy. However, heat loss of photothermal materials still limits the photothermal conversion phenomenon. Herein, we designed bio-inspired hollow carbon microtubes (HCMTs) by one-step carbonization of renewable cotton fibers, which can avoid the complex preparation procedures of the template method. Similar to polar bears, the hollow construction can efficiently reduce heat loss, which improves the utilization of light and photothermal property. The HCMTs can be applied on a variety of substrates to obtain multifunctional photothermal protective coatings. The temperature of the coating can rapidly warm up to 97.7 °C under 1 kW/m sun irradiation. In addition, the coatings show excellent superhydrophobic property (CA of 161.5 ± 0.9°), which can prevent the adhesion of the contaminant and maintain the long-time photothermal property of the surface. Also, the coating is able to withstand sandpaper abrasion, repeat tape-peeling, and tribological friction without losing superhydrophobic properties, indicating remarkable mechanical stability. Furthermore, the coating can withstand high-temperature calcination (400 °C), long-time UV radiation, and corrosive liquid erosion, which exhibits prominent chemical stability. More importantly, the combination of active deicing and passive anti-icing of the coating can effectively prevent the formation and accumulation of ice on the surface. The outstanding environmental adaptability can greatly extend its lifespan and meet the long-term service conditions.
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http://dx.doi.org/10.1021/acsami.2c07232 | DOI Listing |
Cyborg Bionic Syst
July 2024
Department of Mechanical Engineering, University of Coimbra, CEMMPRE, ARISE, Coimbra, Portugal.
Bio-inspired soft robots have already shown the ability to handle uncertainty and adapt to unstructured environments. However, their availability is partially restricted by time-consuming, costly, and highly supervised design-fabrication processes, often based on resource-intensive iterative workflows. Here, we propose an integrated approach targeting the design and fabrication of pneumatic soft actuators in a single casting step.
View Article and Find Full Text PDFIEEE Trans Robot
February 2024
Department of Mechanical and Aerospace Engineering, University of California, San Diego, La Jolla, CA 92093 USA.
A new subclass of soft robot, known as tip-extending or "vine" robots, consists of long inflatable devices that move through the environment by extending from the tip. A key requirement for many applications of these robots is a working channel-a hollow tube through the core of the robot for passing tools, sensors, fluids, etc. While working channels have been proposed in a few vine robots, it remains an open challenge to create miniaturized vine robots (diameter < 1 cm) with working channels that enable continuous access through the core.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2024
Department of Chemistry, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200438, P. R. China.
In the field of sustainable chemistry, it is still a significant challenge to realize efficient light-powered space-confined catalysis and propulsion due to the limited solar absorption efficiency and the low mass and heat transfer efficiency. Here, novel semiconductor TiO nanorockets with asymmetric, hollow, mesoporous, and double-layer structures are successfully constructed through a facile interfacial superassembly strategy. The high concentration of defects and unique topological features improve light scattering and reduce the distance for charge migration and directed charge separation, resulting in enhanced light harvesting in the confined nanospace and resulting in enhanced catalysis and self-propulsion.
View Article and Find Full Text PDFAdv Mater
June 2024
Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Ultrathin perfect absorber (UPA) enables efficient photothermal conversion (PC) in renewable chemical and energy systems. However, it is challenging so far to obtain efficient absorption with thickness significantly less than the wavelength, especially considering the common view that an ultrathin film can absorb at most 50% of incident light. Here, a highly light-absorbing and mechanically stable UPA is reported by learning from the honeycomb mirror design of the crab compound eyes.
View Article and Find Full Text PDFSmall
January 2024
Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Advanced Innovation Center for Biomedical Engineering, School of Chemistry, Beihang University, Beijing, 100191, P. R. China.
The issues of polysulfide shuttling and lethargic sulfur redox reaction (SROR) kinetics are the toughest obstacles of lithium-sulfur (Li-S) battery. Herein, integrating the merits of increased density of metal sites and synergistic catalytic effect, a unique single-atom catalyst (SAC) with nonmetallic-bonding Fe-Mn diatomic pairs anchored on hollow nitrogen-doped carbonaceous nanodisk (denoted as FeMnDA@NC) is successfully constructed and well characterized by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy, X-ray absorption spectroscopy, etc. Density functional theory calculation indicates that the Fe-Mn diatomic pairs can effectively inhibit the shuttle effect by enhancing the adsorption ability retarding the polysulfide migration and accelerate the SROR kinetics.
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