design of graphene plasmonic hot-spots.

Nanoscale Adv

Scuola Normale Superiore Piazza dei Cavalieri 7 56126 Pisa Italy

Published: May 2022

We propose a route for the rational design of engineered graphene-based nanostructures, which feature enormously enhanced electric fields in their proximity. Geometrical arrangements are inspired by nanopatterns allowing single molecule detection on noble metal substrates, and are conceived to take into account experimental feasibility and ease in fabrication processes. The attention is especially focused on enhancement effects occurring close to edge defects and grain boundaries, which are usually present in graphene samples. There, very localized hot-spots are created, with enhancement factors comparable to noble metal substrates, thus potentially paving the way for single molecule detection from graphene-based substrates.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9113057PMC
http://dx.doi.org/10.1039/d2na00088aDOI Listing

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