In the field of liquid crystals, it is well known that rodlike molecules interacting via long-range attractive interactions or short-range repulsive potentials can exhibit orientational order. In this work, we are interested in what would happen to systems of rodlike particles interacting via a long-range repulsive potential. In our model, each particle consists of a number of point dipoles uniformly distributed along the particle length, with all dipoles pointing along the z axis so that the rodlike particles repel each other when they lie in the x-y plane. Dipoles from different particles interact via an r^{-3} potential, where r is the distance between the dipoles. We have considered two model systems, each with N particles in a unit cell with periodic boundary conditions. In the first, particle centers are fixed on a square or triangular lattice but they are free to rotate. In the second, particles are free to translate as well as rotate in cells with variable shapes. Here they self-assemble to form configurations where the stress tensors are isotropic. Our numerical results show that, at low temperatures, the particles tend to form stripes with alternating orientations, resembling herringbone patterns or the anticlinic Sm-C_{A} liquid crystal phase.
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http://dx.doi.org/10.1103/PhysRevE.105.054702 | DOI Listing |
Phys Rev Lett
December 2024
School of Physical Sciences, University of Chinese Academy of Sciences (UCAS), Beijing 100049, China.
It is well established that the long-range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance H is screened by an intervening electrolyte. Here we show how this interaction is modified when an electric field of strength E is applied parallel to the dielectric boundaries, leading to a nonequilibrium steady state with a current. The presence of the field induces a long-range thermal repulsive interaction, scaling just like the thermal Casimir interaction between dielectrics without the intervening electrolyte, i.
View Article and Find Full Text PDFACS Nano
December 2024
Department of Chemistry, James Franck Institute, and Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States.
Electrostatically stabilized nanocrystals (NCs) and, in particular, quantum dots (QDs) hold promise for forming strongly coupled superlattices due to their compact and electronically conductive surface ligands. However, studies of the colloidal dispersion and interparticle interactions of electrostatically stabilized sub-10 nm NCs have been limited, hindering the optimization of their colloidal stability and self-assembly. In this study, we employed small-angle X-ray scattering (SAXS) experiments to investigate the interparticle interactions and arrangement of PbS QDs with thiostannate ligands (PbS-SnS) in polar solvents.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, USA.
The electrostatic correlations between ions profoundly influence the structure and forces within electrical double layers. Here, we apply the modified Gaussian renormalized fluctuation theory to investigate the counter-intuitive phenomenon of repulsion between two oppositely charged surfaces and discuss its relationship with overcharging. By accurately accounting for the effect of spatially varying ion-ion correlations, we capture these repulsive forces for divalent, trivalent, as well as tetravalent ions, in quantitative agreement with reported simulation results.
View Article and Find Full Text PDFPhys Rev E
October 2024
School of Physics, Beijing Institute of Technology, Beijing 100081, China.
J Phys Condens Matter
November 2024
Key Laboratory of Soft Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
We revisit the equilibrium statistical mechanics of a classical fluid of point-like particles with repulsive power-law pair interactions, focusing on density and energy fluctuations at finite temperature. Such long-range interactions, decaying with inter-particle distanceas1/rsindimensions, are known to fall into two qualitatively different categories. For < ('strongly' long-range interactions) there are screening of correlations and suppression of large-wavelength density fluctuations (hyperuniformity).
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