MOF-5 with a Zn(ii) cluster and terephthalic acid is a distinctive porous material among the metal-organic frameworks (MOFs), with unique physical, chemical and mechanical properties. MOF-5 based composites possess ample applications in modern chemistry. Huge surface area, suitable pore dimensions and scope of tunability make MOF-5 noteworthy in advanced materials. The extensive features of MOF-5 provided an opportunity for researchers to explore atomic/molecular scale materials. Various MOF-5 based composites have been designed with revamped properties appropriate to the application by altering and fabricating MOF-5 or using a post-synthetic approach. Surface modification the dispersion and impregnation of active substances into the pores of MOF-5 enhances its applicability. The boundless topologies and morphologies of MOF-5 combined with other chemical entities has provided opportunities in various fields, including catalysis, gas storage and sensors. The present review illuminates the leading role of MOF-5 and its composites in contemporary applications based on the current literature in heterogeneous catalysis, H and CO storage and sensors.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9097495 | PMC |
| http://dx.doi.org/10.1039/d2ra01505f | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Room-temperature synthesis of FeO@MOF-5 magnetic hybrid as an efficient catalyst for the one-pot green synthesis of tetrahydropyridines.
Sci Rep
December 2024
Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University, Hamedan, Iran.
In recent two decades, considerable efforts have been devoted to the room-temperature green syntheses of metal-organic frameworks (MOFs) to reduce energy consumption and increase safety. It could improve some properties (e.g.
View Article and Find Full Text PDFEquipartitioning of Molecular Degrees of Freedom in MD Simulations of Gaseous Systems via an Advanced Thermostatization Strategy.
J Chem Theory Comput
December 2024
Theoretical Chemistry Division, Institute of General, Inorganic and Theoretical Chemistry, Center for Chemistry and Biomedicine, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck, Austria.
This work introduces a dedicated thermostatization strategy for molecular dynamics simulations of gaseous systems. The proposed thermostat is based on the stochastic canonical velocity rescaling approach by Bussi and co-workers and is capable of ensuring an equal distribution of the kinetic energy among the translational, rotational, and vibrational degrees of freedom. The outlined framework ensures the correct treatment of the kinetic energy in gaseous systems, which is typically not the case in standard approaches due to the limited number of collisions between particles associated with a large free mean path.
View Article and Find Full Text PDFA Dual-Functional and Efficient MOF-5@MWCNTs Electrochemical Sensing Device for the Measurement of Trace-Level Acetaminophenol and Dopamine.
Molecules
November 2024
Department of Chemistry, Xinzhou Normal University, Xinzhou 034000, China.
The design and construction of dual-functional and high-efficiency electrochemical sensors are necessary for quantitative detection. In this work, a zinc-based metal-organic framework (MOF-5) and multi-walled carbon nanotubes (MWCNTs) were combined in situ through a simple solvothermal reaction to obtain an MOF-5@MWCNTs composite. The composite exhibits a large surface area, hierarchical pore structure, excellent conductivity, and enhanced electrochemical performance in the detection of acetaminophenol (AP) and dopamine (DA).
View Article and Find Full Text PDFImmobilization of lipase on metal-organic frameworks and investigation of their catalytic properties and stability.
Eng Microbiol
December 2024
Department of Organic Chemistry, Faculty of Chemistry, Shahid Beheshti University, G.C., Tehran, Iran.
Surface adsorption is a convenient and readily available method for immobilizing enzymes on metal-organic frameworks (MOFs). Metal-organic framework-5 (MOF-5), isoreticular metal-organic frameworks-3 (IRMOF-3), and multivariate analysis of MOF-5/IRMOF-3 (MMI) with a half-amino group (-NH) were prepared in this study. lipase (TLL) was chosen as a commercially available enzyme for immobilization on the surfaces of these MOFs.
View Article and Find Full Text PDFSynthesis of metal-organic framework-luminescent guest (MOF@LG) composites and their applications in environmental health sensing: A mini review.
Talanta
February 2025
Research Center of Gansu Military and Civilian Integration Advanced Structural Materials, Lanzhou, 730070, PR China; Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Lanzhou, 730070, PR China; Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, PR China. Electronic address:
Metal-organic framework (MOF) materials are three-dimensional structures formed by the combination of metal ions and organic ligands. So far, various typical metal organic framework materials have emerged, such as ZIF-8, MOF-5, UIO-66, etc. These traditional MOF materials have the advantages of simple synthesis, high porosity, and high stability, and have great research potential in the field of fluorescence sensing.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!