The photoactivation mechanism of Os(CO) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os(CO) with a ligand vacancy at the axial position.
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| http://dx.doi.org/10.1039/d2cc02438a | DOI Listing |
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