Sudan I, a lipophilic azo dye -dye, is desirable and urgent to be accurate detected due to its increasing levels and high toxicity in food and environmental monitoring and analysis. Herein, a sensitive electrochemical sensor for Sudan I was established based on a new KPWFe(HO)O functionalized carbon nanomaterials (FePW-GNPS). The electrode modified nanocomposite, FePW-GNPS, was successfully fabricated and characterized by FTIR, SEM and UV-vis. The effective combination of FePW and graphene exhibited high electrocatalytic activity towards the oxidation of Sudan I, promote charge transfer, and more sensing sites. Under optimized experimental conditions, the proposed differential pulse voltammetry (DPV) showed excellent analytical performances for Sudan I with the limit of detection (LOD) of 5 nM (S/N = 3), the sensitivity of 13.10 μA·μMcm at the 0.005-2 μM and 0.39 μA·μMcm at 10-200 μM. The stability and reproducibility make the electrochemical sensor suitable for detecting the Sudan I in food.
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| http://dx.doi.org/10.1016/j.fct.2022.113222 | DOI Listing |
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