Pyrochlore phosphors have shown their worth in modern day lighting in the last few years. Colour tunability of the phosphor is one of the modern techniques used to obtain white light-emitting diodes (WLEDs). In the proposed work, Y Zr O :Sm ,Eu phosphors were investigated for WLED applications as well as display devices. A convectional solid-state diffusion method was used to synthesize the proposed phosphors. X-ray diffraction of the proposed phosphors was performed and compared with the standard Inorganic Crystal Structure Database. The crystal structure of the sample was cubic in nature, obtained from Rietveld refinement. Vibrational and morphological studies on the samples were carried out using Fourier transform infrared spectroscopy and scanning electron microscopy analysis. The photoluminescence study of the colour tunable phosphor showed the characteristic peak of Sm together with the two sharp peaks of Eu ions. Greenish yellow to red colour tunability was observed in the proposed phosphor with enhancement of Eu ions. All these results showed the worth of this sample for WLEDs applications as well as in display devices.
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http://dx.doi.org/10.1002/bio.4305 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
School of Physics and Optoelectronic Engineering, Ludong University, Yantai 264000, China.
Constructing multifunctional phosphors grounded in the intricate relationship between energy level structures and luminescent properties has captivated researchers in the luminescent material field. Herein, using the embedded cluster multiconfigurational ab initio method, the energy levels of Bi in the SrLaGaO host at different geometries were calculated, which results in the establishment of complete configurational coordinate curves, yielding breathing mode vibrational frequencies and equilibrium bond lengths for all excited states. These curves supply deep insight into the luminescence properties of Bi-doped phosphors and highlight the impact of ions in the second coordination sphere on luminescence.
View Article and Find Full Text PDFAnal Methods
December 2024
Jiaxing Key Laboratory of Molecular Recognition and Sensing, College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, P. R. China.
The greenish-yellow synthetic dye quinoline yellow (Qy) is widely used in the food and pharmaceutical industries. However, this dye may lead to health and environmental problems. Therefore, investigating how Qy interacts with biological macromolecules is of great interest.
View Article and Find Full Text PDFForensic Sci Med Pathol
December 2024
University Hospital Schleswig-Holstein, Institute of Legal Medicine, Kahlhorststr. 31-35, Building 89, Campus Kiel: Arnold-Heller-Str. 3, Building 28, 23562, 24105, Lübeck, Kiel, Germany.
The intestinal content of newborns is known as meconium, usually described as a black-greenish slimy substance. However, in rare cases, meconium might be yellow. This is of great relevance with regard to the forensic assessment of life birth, i.
View Article and Find Full Text PDFMikrochim Acta
December 2024
Department of Chemistry, College of Science, University of Sulaimani, Qliasan St. 46002, Sulaymaniyah, Kurdistan Region, Iraq.
An efficient dual-state blue-emitting zinc-based metal-organic frameworks (MOFs), designated as UoZ-8 has been developed. Coordination-induced emission causes the UoZ-8 to give the blue emission in both solid and dispersed form in liquid. Upon the addition of tetracycline (TC), a noticeable shift from blue emission to greenish-yellow emission occurred, with a marked increase in intensity, which was attributed to the inner filter effect accompanied by aggregation-induced emission (IFE-AIE).
View Article and Find Full Text PDFACS Mater Au
November 2024
Materials Research Centre, Indian Institute of Science, Bangalore 560012, India.
Moisture-sensitive fluorescent emitters are a class of smart materials that can change their emission behavior upon exposure to water. In this study, we have synthesized two highly fluorescent organic emitters, 4BPy-PTA and 2BPy-PTA, and showed how moisture sensitivity can be enhanced by molecular design modification. Owing to the different nitrogen atom positions in the acceptor units, the emitters show different degrees of moisture sensitivity.
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